The Chemical History of a Candle

Michael Faraday

• Publisher: Dover Publications
• Year: 2012
• ISBN:
  9780486171142
• Topic: Biological Sciences
• Subtopic: Natural History
• Index: Biological Sciences

One of the greatest experimental scientists of all time, Michael Faraday (1791–1867) developed the first electric motor, electric generator, and dynamo — essentially creating the science of electrochemistry. This book, the result of six lectures he delivered to young students at London's Royal Institution, concerns another form of energy — candlelight.
Faraday titled the lectures "The Chemical History of a Candle, " choosing the subject because, as he explained, "There is not a law under which any part of this universe is governed which does not come into play and is not touched upon [during the time a candle burns]."
That statement is the foundation for a book that describes, with great clarity, the components, function and weight of the atmosphere; the function of a candle wick; capillary attraction; the carbon content in oxygen and living bodies; the production of carbon dioxide from coal gas and sugar; the properties of carbonic acid; respiration and its analogy to the burning of a candle; and much more. There is also a chapter comprising Faraday's "Lecture on Platinum."
A useful classroom teaching tool, this classic text will also appeal to a wide audience interested in scientific inquiry.

LECTURES ON THE CHEMICAL HISTORY OF A CANDLE.

LECTURE I.

A CANDLE: THE FLAME—ITS SOURCES—STRUCTURE—MOBILITY—BRIGHTNESS.

I PURPOSE, in return for the honor you do us by coming to see what are our proceedings here, to bring before you, in the course of these lectures, the Chemical History of a Candle. I have taken this subject on a former occasion, and, were it left to my own will, I should prefer to repeat it almost every year, so abundant is the interest that attaches itself to the subject, so wonderful are the varieties of outlet which it offers into the various departments of philosophy. There is not a law under which any part of this universe is governed which does not come into play and is touched upon in these phenomena. There is no better, there is no more open door by which you can enter into the study of natural philosophy than by considering the physical phenomena of a candle. I trust, therefore, I shall not disappoint you in choosing this for my subject rather than any newer topic, which could not be better, were it even so good.

And, before proceeding, let me say this also: that, though our subject be so great, and our intention that of treating it honestly, seriously, and philosophically, yet I mean to pass away from all those who are seniors among us. I claim the privilege of speaking to juveniles as a juvenile myself. I have done so on former occasions, and, if you please, I shall do so again. And, though I stand here with the knowledge of having the words I utter given to the world, yet that shall not deter me from speaking in the same familiar way to those whom I esteem nearest to me on this occasion.

And now, my boys and girls, I must first tell you of what candles are made. Some are great curiosities. I have here some bits of timber, branches of trees particularly famous for their burning. And here you see a piece of that very curious substance, taken out of some of the bogs in Ireland, called candle-wood; a hard, strong, excellent wood, evidently fitted for good work as a register of force, and yet, withal, burning so well that where it is found they make splinters of it, and torches, since it burns like a candle, and gives a very good light indeed. And in this wood we have one of the most beautiful illustrations of the general nature of a candle that I can possibly give. The fuel provided, the means of bringing that fuel to the place of chemical action, the regular and gradual supply of air to that place of action—heat and light—all produced by a little piece of wood of this kind, forming, in fact, a natural candle.

But we must speak of candles as they are in commerce. Here are a couple of candles commonly called dips. They are made of lengths of cotton cut off, hung up by a loop, dipped into melted tallow, taken out again and cooled, then redipped, until there is an accumulation of tallow round the cotton. In order that you may have an idea of the various characters of these candles, you see these which I hold in my hand—they are very small and very curious. They are, or were, the candles used by the miners in coal mines. In olden times the miner had to find his own candles, and it was supposed that a small candle would not so soon set fire to the fire-damp in the coal mines as a large one; and for that reason, as well as for economy’s sake, he had candles made of this sort—20, 30, 40, or 60 to the pound. They have been replaced since then by the steel-mill, and then by the Davy lamp, and other safety-lamps of various kinds. I have here a candle that was taken out of the Royal George,¹ it is said, by Colonel Pasley. It has been sunk in the sea for many years, subject to the action of salt water. It shows you how well candles may be preserved; for, though it is cracked about and broken a good deal, yet when lighted it goes on burning regularly, and the tallow resumes its natural condition as soon as it is fused.

Mr. Field, of Lambeth, has supplied me abundantly with beautiful illustrations of the candle and its materials; I shall therefore now refer to them. And, first, there is the suet—the fat of the ox—Russian tallow, I believe, employed in the manufacture of these dips, which Gay-Lussac, or some one who intrusted him with his knowledge, converted into that beautiful substance, stearin, which you see lying beside it. A candle, you know, is not now a greasy thing like an ordinary tallow candle, but a clean thing, and you may almost scrape off and pulverize the drops which fall from it without soiling any thing. This is the process he adopted :² The fat or tallow is first boiled with quick-lime, and made into a soap, and then the soap is decomposed by sulphuric acid, which takes away the lime, and leaves the fat rearranged as stearic acid, while a quantity of glycerin is produced at the same time. Glycerin —absolutely a sugar, or a substance similar to sugar—comes out of the tallow in this chemical change. The oil is then pressed out of it; and you see here this series of pressed cakes, showing how beautifully the impurities are carried out by the oily part as the pressure goes on increasing, and at last you have left that substance, which is melted, and cast into candles as here represented. The candle I have in my hand is a stearin candle, made of stearin from tallow in the way I have told you. Then here is a sperm candle, which comes from the purified oil of the spermaceti whale. Here, also, are yellow bees’-wax and refined bees’-wax, from which candles are made. Here, too, is that curious substance called paraffine, and some paraffine candles, made of paraffine obtained from the bogs of Ireland. I have here also a substance brought from Japan since we have forced an entrance into that out-of-the-way place—a sort of wax which a kind friend has sent me, and which forms a new material for the manufacture of candles.

And how are these candles made? I have told you about dips, and I will show you how moulds are made. Let us imagine any of these candles to be made of materials which can be cast. “Cast!” you say. “Why, a candle is a thing that melts, and surely if you can melt it you can cast it.” Not so. It is wonderful, in the progress of manufacture, and in the consideration of the means best fitted to produce the required result, how things turn up which one would not expect beforehand. Candles can not always be cast. A wax candle can never be cast. It is made by a particular process which I can illustrate in a minute or two, but I must not spend much time on it. Wax is a thing which, burning so well, and melting so easily in a candle, can not be cast. However, let us take a material that can be cast. Here is a frame, with a number of moulds fastened in it. The first thing to be done is to put a wick through them. Here is one—a plaited wick, which does not require snuffing³—supported by a little wire. It goes to the bottom, where it is pegged in; the little peg holding the cotton tight, and stopping the aperture so that nothing fluid shall run out. At the upper part there is a little bar placed across, which stretches the cotton and holds it in the mould. The tallow is then melted, and the moulds are filled. After a certain time, when the moulds are cool, the excess of tallow is poured off at one corner, and then cleaned off altogether, and the ends of the wick cut away. The candles alone then remain in the mould, and you have only to upset them, as I am doing, when out they tumble, for the candles are made in the form of cones, being narrower at the top than at the bottom; so that, what with their form and their own shrinking, they only need a little shaking and out they fall. In the same way are made these candles of stearin and of paraffine. It is a curious thing to see how wax candles are made. A lot of cottons are hung upon frames, as you see here, and covered with metal tags at the ends to keep the wax from covering the cotton in those places. These are carried to a heater, where the wax is melted. As you see, the frames can turn round; and, as they turn, a man takes a vessel of wax and pours it first down one, and then the next, and the next, and so on. When he has gone once round, if it is sufficiently cool, he gives the first a second coat, and so on until they are all of the required thickness. When they have been thus clothed, or fed, or made up to that thickness, they are taken off and placed elsewhere. I have here, by the kindness of Mr. Field, several specimens of these candles. Here is one only half finished. They are then taken down and well rolled upon a fine stone slab, and the conical top is moulded by properly shaped tubes, and the bottoms cut off and trimmed. This is done so beautifully that they can make candles in this way weighing exactly four or six to the pound, or any number they please.

We must not, however, take up more time about the mere manufacture, but go a little farther into the matter. I have not yet referred you to luxuries in candles (for there is such a thing as luxury in candles). See how beautifully these are colored; you see here mauve, Magenta, and all the chemical colors recently introduced, applied to candles. You observe, also, different forms employed. Here is a fluted pillar most beautifully shaped; and I have also here some candles sent me by Mr. Pearsall, which are ornamented with designs upon them, so that, as they burn, you have, as it were, a glowing sun above, and a bouquet of flowers beneath. All, however, that is fine and beautiful is not useful. These fluted candles, pretty as they are, are bad candles; they are bad because of their external shape. Nevertheless, I show you these specimens, sent to me from kind friends on all sides, that you may see what is done and what may be done in this or that direction; although, as I have said, when we come to these refinements, we are obliged to sacrifice a little in utility.

Now as to the light of the candle. We will light one or two, and set them at work in the performance of their proper functions. You observe a candle is a very different thing from a lamp. With a lamp you take a little oil, fill your vessel, put in a little moss or some cotton prepared by artificial means, and then light the top of the wick. When the flame runs down the cotton to the oil, it gets extinguished, but it goes on burning in the part above. Now I have no doubt you will ask how it is that the oil which will not burn of itself gets up to the top of the cotton, where it will burn. We shall presently examine that; but there is a much more wonderful thing about the burning of a candle than this. You have here a solid substance with no vessel to contain it; and how is it that this solid substance can get up to the place where the flame is? How is it that this solid gets there, it not being a fluid? or, when it is made a fluid, then how is it that it keeps together? This is a wonderful thing about a candle.

We have here a good deal of wind, which will help us in some of our illustrations, but tease us in others; for the sake, therefore, of a little regularity, and to simplify the matter, I shall make a quiet flame, for who can study a subject when there are difficulties in the way not belonging to it? Here is a clever invention of some costermonger or street-stander in the market-place for the shading of their candles on Saturday nights, when they are selling their greens, or potatoes, or fish. I have very often admired it. They put a lamp-glass round the candle, supported on a kind of gallery, which clasps it, and it can be slipped up and down as required. By the use of this lamp-glass, employed in the same way, you have a steady flame, which you can look at, and carefully examine, as I hope you will do, at home.

You see then, in the first instance, that a beautiful cup is formed. As the air comes to the candle, it moves upward by the force of the current which the heat of the candle produces, and it so cools all the sides of the wax, tallow, or fuel as to keep the edge much cooler than the part within; the part within melts by the flame that runs down the wick as far as it can go before it is extinguished, but the part on the outside does not melt. If I made a current in one direction, my cup would be lop-sided, and the fluid would consequently run over; for the same force of gravity which holds worlds together holds this fluid in a horizontal position, and if the cup be not horizontal, of course the fluid will run away in guttering. You see, therefore, that the cup is formed by this beautifully regular ascending current of air playing upon all sides, which keeps the exterior of the candle cool. No fuel would serve for a candle which has not the property of giving this cup, except such fuel as the Irish bog-wood, where the material itself is like a sponge and holds its own fuel. You see now why you would have had such a bad result if you were to burn these beautiful candles that I have shown you, which are irregular, intermittent in their shape, and can not, therefore, have that nicely-formed edge to the cup which is the great beauty in a candle. I hope you will now see that the perfection of a process—that is, its utility—is the better point of beauty about it. It is not the best looking thing, but the best acting thing, which is the most advantageous to us. This good-looking candle is a bad-burning one. There will be a guttering round about it because of the irregularity of the stream of air and the badness of the cup which is formed thereby. You may see some pretty examples (and I trust you will notice these instances) of the action of the ascending current when you have a little gutter run down the side of a candle, making it thicker there than it is elsewhere. As the candle goes on burning, that keeps its place and forms a little pillar sticking up by the side, because, as it rises higher above the rest of the wax or fuel, the air gets better round it, and it is more cooled and better able to resist the action of the heat at a little distance. Now the greatest mistakes and faults with regard to candles, as in many other things, often bring with them instruction which we should not receive if they had not occurred. We come here to be philosophers, and I hope you will always remember that whenever a result happens, especially if it be new, you should say, “What is the cause? Why does it occur?” and you will, in the course of time, find out the reason.

Then there is another point about these candles which will answer a question—that is, as to the way in which this fluid gets out of the cup, up the wick, and into the place of combustion. You know that the flames on these burning wicks in candles made of bees’-wax, stearin, or spermaceti, do not run down to the wax or other matter, and melt it all away, but keep to their own right place. They are fenced off from the fluid below, and do not encroach on the cup at the sides. I can not imagine a more beautiful example than the condition of adjustment under which a candle makes one part subserve to the other to the very end of its action. A combustible thing like that, burning away gradually, never being intruded upon by the flame, is a very beautiful sight, especially when you come to learn what a vigorous thing flame is—what power it has of destroying the wax itself when it gets hold of it, and of disturbing its proper form if it come only too near.

But how does the flame get hold of the fuel? There is a beautiful point about that—capillary attraction.⁴ “Capillary attraction!” you say —“the attraction of hairs.” Well, never mind the name; it was given in old times, before we had a good understanding of what the real power was. It is by what is called capillary attraction that the fuel is conveyed to the part where combustion goes on, and is deposited there, not in a careless way, but very beautifully in the very midst of the centre of action, which takes place around it. Now I am going to give you one or two instances of capillary attraction. It is that kind of action or attraction which makes two things that do not dissolve in each other still hold together. When you wash your hands, you wet them thoroughly; you take a little soap to make the adhesion better, and you find your hand remains wet. This is by that kind of attraction of which I am about to speak. And, what is more, if your hands are not soiled (as they almost always are by the usages of life), if you put your finger into a little warm water, the water will creep a little way up the finger, though you may n...