High-Pressure Fluid Phase Equilibria

Phenomenology and Computation

Ulrich K Deiters, Thomas Kraska

• Publisher: Elsevier
• Year: 2023
• Print ISBN:
  9780443132803
• eBook ISBN:
  9780443132810
• Edition: 2
• Topic: Physical Sciences
• Subtopic: Physical & Theoretical Chemistry

High pressures play a more and more important role in modern technology. Examples are the supercritical fluid extraction of medical drugs and dyes from biological material, the handling of compressed or liquefied gases (including natural gas or hydrogen), the operation of modern thermal power plants, or various technical processes for controlled particle formation. High-Pressure Fluid Phase Equilibria, Second Edition enables understanding of the complicated phase behaviour that fluid or fluid mixtures (liquids, gases, or supercritical phases) can exhibit at elevated pressures. The underlying thermodynamic equations are explained, and robust algorithms for the computation of such equilibria (including solid–fluid equilibria) are proposed. Since the publication of the first edition of this book there have been many new developments, for instance differential equation methods for the computation of phase equilibria, accurate numerical differentiation, high-precision equations of state (e.g., the GERG model). Moreover, more detail and explanation has been added on important topics that were only briefly examined in the original book to better assist the reader, such as expansion processes and chemical reactions). The book remains invaluable as a single resource for grasping the intricacies of fluid phase behaviour. It enables readers to write or improve their own computer programs for the calculation of phase equilibria. It will appeal to graduate students of chemical engineering and university research staff involved in chemical engineering of supercritical fluids or the physical chemistry of fluids; the book can also serve as the basis of lectures or advanced students' seminars. - Comprehensively presents the complex world of phase equilibria (binary and ternary) and the various methods for computing phase equilibria, whilst carefully considering the relevant pressure and temperature ranges - Introduces phase diagram classes, how to recognize them, and how to identify their characteristic features - Presents rational nomenclature of binary fluid phase diagrams - Includes problems and solutions for self-testing, exercises, or seminars New to this Edition: - Presentation of the phase equilibria models is extended and expanded - There are now more descriptions on more equations of state, especially the PCSAFT EoS - Features new chapter on nonisothermal applications and chemically reactive systems and extensive updates and additions to all existing chapters

Table of contents

• High-Pressure Fluid Phase Equilibria
• Cover
• Title Page
• Table of Contents
• Copyright
• Dedication
• Biography
• Preface
• Chapter 1 Introduction
• Chapter 2 Phenomenology of phase diagrams
• Chapter 3 Experimental observation of phase equilibria
• Chapter 4 Thermodynamic variables and functions
• Chapter 5 Stability and equilibrium
• Chapter 6 Non-isothermal applications and chemically reactive systems
• Chapter 7 Solid–fluid equilibrium
• Chapter 8 Equations of state for pure fluids
• Chapter 9 Equations of state for mixtures
• Chapter 10 Global phase diagrams
• Appendix A Algebraic and numeric methods
• Appendix B Theorems and proofs
• Appendix C Equations of state: auxiliary equations for programming
• Appendix D Solutions of the problems
• References
• Index