Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.

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Yes, you can access Oxidation of Organic Compounds by N. M. Emanuel,G. E. Zaikov,Z. K. Maizus, M. M. Hirschler in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Chemistry. We have over one million books available in our catalogue for you to explore.

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Index

Front Cover
Oxidation of Organic Compounds: Medium Effects in Radical Reactions
Copyright Page
Table of Contents
Preface
Preface to the English Edition
Epigraph
Introduction
CHAPTER 1. Mechanism of the Liquid Phase Oxidation of Organic Compounds
CHAPTER 2. Some Methods for Studying the Mechanism of Oxidation Reactions
CHAPTER 3. The Role of Solvation in Chemical Reaction Kinetics
CHAPTER 4. The Role of the Medium in Chain-initiation Reactions
CHAPTER 5. Role of Non-specific Solvation in Chain-propagation and Chain-termination Reactions
CHAPTER 6. The Role of Specific Solvation in Chain-propagation and Chain-termination Reactions
CHAPTER 7. The Role of Solvation in Chain-termination Reactions in Inhibitors
CHAPTER 8. The Causes of the Difference Between the Composition of Products Formed in the Oxidation of Organic Substances in the Vapour and Liquid Phases
CHAPTER 9. Influence of Solvents on the Rate and Direction of Oxidation Processes
CHAPTER 10. Some Special Features of the Kinetic Laws and the Mechanism of Oxidation of Solid Polymers
Appendix
Subject Index

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