N-Heterocyclic Carbenes

From Laboratory Curiosities to Efficient Synthetic Tools

Silvia Diez-Gonzalez

• Publisher: Royal Society of Chemistry
• Year: 2016
• eBook ISBN: 9781782626817
• Edition: 2
• Topic: Physical Sciences
• Subtopic: Chemistry
• Index: Chemistry

In less than 20 years N-heterocyclic carbenes (NHCs) have become well-established ancillary ligands for the preparation of transition metal-based catalysts. This is mainly due to the fact that NHCs tend to bind strongly to metal centres, avoiding the need of excess ligand in catalytic reactions. Also, NHC?metal complexes are often insensitive to air and moisture, and have proven remarkably resistant to oxidation. This book showcases the wide variety of applications of NHCs in different chemistry fields beyond being simple phosphine mimics. This second edition has been updated throughout, and now includes a new chapter on NHC?main group element complexes. It covers the synthesis of NHC ligands and their corresponding metal complexes, as well as their bonding and stereoelectronic properties and applications in catalysis. This is complemented by related topics such as organocatalysis and biologically active complexes. Written for organic and inorganic chemists, this book is ideal for postgraduates, researchers and industrialists.

Table of contents

• Cover
• N-Heterocyclic Carbenes From Laboratory Curiosities to Efficient Synthetic Tools 2nd Edition
• Foreword
• Preface
• Dedication
• Abbreviations and Acronyms
• Contents
• Chapter 1 - Introduction to N-Heterocyclic Carbenes: Synthesis and Stereoelectronic Parameters
• Chapter 2 - Synthesis, Activation, and Decomposition of N-Heterocyclic Carbene-Containing Complexes
• Chapter 3 - Non-Classical N-Heterocyclic Carbene Complexes
• Chapter 4 - Computational Studies on the Reactivity of Transition Metal Complexes with N-Heterocyclic Carbene Ligands
• Chapter 5 - Main Group Complexes with N-Heterocyclic Carbenes: Bonding, Stabilization and Applications in Catalysis
• Chapter 6 - Rare Earth Metal Complexes with N-Heterocyclic Carbenes
• Chapter 7 - NHC–Iron, Ruthenium and Osmium Complexes in Catalysis
• Chapter 8 - NHC–Cobalt, –Rhodium, and –Iridium Complexes in Catalysis
• Chapter 9 - NHC–Palladium Complexes in Catalysis
• Chapter 10 - NHC–Nickel and Platinum Complexes in Catalysis
• Chapter 11 - NHC–Copper, –Silver and –Gold Complexes in Catalysis
• Chapter 12 - Oxidation Reactions with NHC Metal Complexes
• Chapter 13 - Reduction Reactions with NHC-Bearing Complexes
• Chapter 14 - N-Heterocyclic Carbenes as Organic Catalysts
• Chapter 15 - Biologically Active N-Heterocyclic Carbene–Metal Complexes
• Subject Index