- English
- ePUB (mobile friendly)
- Available on iOS & Android
eBook - ePub
About this book
Uniquely describes both the crystallography and properties of perovskite related materials.
- Practical applications in solar cells, microelectronics and telecommunications
- Interdisciplinary topic drawing on materials science, chemistry, physics, and geology
- Contains problems and answers to enhance knowledge retentionĀ
Frequently asked questions
Yes, you can cancel anytime from the Subscription tab in your account settings on the Perlego website. Your subscription will stay active until the end of your current billing period. Learn how to cancel your subscription.
No, books cannot be downloaded as external files, such as PDFs, for use outside of Perlego. However, you can download books within the Perlego app for offline reading on mobile or tablet. Learn more here.
Perlego offers two plans: Essential and Complete
- Essential is ideal for learners and professionals who enjoy exploring a wide range of subjects. Access the Essential Library with 800,000+ trusted titles and best-sellers across business, personal growth, and the humanities. Includes unlimited reading time and Standard Read Aloud voice.
- Complete: Perfect for advanced learners and researchers needing full, unrestricted access. Unlock 1.4M+ books across hundreds of subjects, including academic and specialized titles. The Complete Plan also includes advanced features like Premium Read Aloud and Research Assistant.
We are an online textbook subscription service, where you can get access to an entire online library for less than the price of a single book per month. With over 1 million books across 1000+ topics, weāve got you covered! Learn more here.
Look out for the read-aloud symbol on your next book to see if you can listen to it. The read-aloud tool reads text aloud for you, highlighting the text as it is being read. You can pause it, speed it up and slow it down. Learn more here.
Yes! You can use the Perlego app on both iOS or Android devices to read anytime, anywhere ā even offline. Perfect for commutes or when youāre on the go.
Please note we cannot support devices running on iOS 13 and Android 7 or earlier. Learn more about using the app.
Please note we cannot support devices running on iOS 13 and Android 7 or earlier. Learn more about using the app.
Yes, you can access Perovskites by Richard J. D. Tilley in PDF and/or ePUB format, as well as other popular books in Technology & Engineering & Materials Science. We have over one million books available in our catalogue for you to explore.
Information
1
The ABX3 Perovskite Structure
1.1 Perovskites
Perovskite is a mineral of formula CaTiO3. It was discovered in 1839 by the Prussian mineralogist Gustav Rose in mineral deposits in the Ural Mountains and named after the Russian mineralogist Count Lev Aleksevich von Petrovski. Natural crystals have a hardness of 5.5ā6 and a density of 4000ā4300 kg mā3. They are usually dark brown to black, due to impurities, but when pure are clear with a refractive index of approximately 2.38. The crystal structure of this compound, initially thought to be cubic, was later shown to be orthorhombic (Table 1.1).
Table 1.1 Representative ABX3 perovskite phases a
| Phase | Space group b | Unit cell | ||
| a (nm) | b (nm) | c (nm) | ||
| 1, 2 | ||||
| AgMgF3 | C, Pm  | 0.41162 | ||
| CsPbI3 | C, Pm  | 0.62894 | ||
| KCuF3 | T, I4/mcm (140) | 0.56086 | 0.76281 | |
| KMgF3 | C, Pm  | 0.39897 | ||
| KZnF3 | C, Pm  | 0.40560 | ||
| NaMgF3 | O, Pbnm (62) | 0.48904 | 0.52022 | 0.71403 |
| NaFeF3 | O, Pnma (62) | 0.56612 | 0.78801 | 0.54836 |
| NH4ZnF3 | C, Pm  | 0.41162 | ||
| 1, 5 | ||||
| KTaO3 | C, Pm  | 0.40316 | ||
| KNbO3 | O, Amm2 (38) | 0.3971 | 0.5697 | 0.5723 |
| 2, 4 | ||||
| SrTiO3 | C, Pm  | 0.3905 | ||
| BaTiO3 | T, P4mm (99) | 0.39906 | 0.40278 | |
| CaTiO3 | O, Pbmn (62) | 0.54035 | 0.54878 | 0.76626 |
| BaSnO3 | C, Pm  | 0.4117 | ||
| CdSnO3 | O, Pnma (62) | 0.52856 | 0.74501 | 0.51927 |
| CaIrO3 | O, Pbnm (62) | 0.52505 | 0.55929 | 0.76769 |
| PbTiO3 | T, P4mm (99) | 0.3902 | 0.4143 | |
| PbZrO3 | O, Pbam (55) | 0.58822 | 1.17813 | 0.82293 |
| SrCoO3 | C, Pm  | 0.3... | ||
Table of contents
- Cover
- Title Page
- Table of Contents
- Preface
- 1 The ABX3 Perovskite Structure
- 2 ABX3āRelated Structures
- 3 Hexagonal PerovskiteāRelated Structures
- 4 Modular Structures
- 5 Diffusion and Ionic Conductivity
- 6 Dielectric Properties
- 7 Magnetic Properties
- 8 Electronic Conductivity
- 9 Thermal and Optical Properties
- Appendix A: The Bond Valence Model for Perovskites
- Appendix B: Summary of the KrƶgerāVink Defect Notation
- Index
- End User License Agreement