Progress in Inorganic Chemistry, Volume 59

Kenneth D. Karlin

• Publisher: Wiley
• Year: 2014
• Print ISBN:
  9781118870167
• eBook ISBN:
  9781118870037
• Edition: 1
• Topic: Physical Sciences
• Subtopic: Biochemistry

This series provides inorganic chemists and materials scientists with a forum for critical, authoritative evaluations of advances in every area of the discipline. Volume 59 continues to report recent advances with a significant, up-to-date selection of contributions by internationally-recognized researchers.

The chapters of this volume are devoted to the following topics:
• Iron Catalysis in Synthetic Chemistry
• A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
• Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA.
• Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
• Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
• Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
• Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations

Iron Catalysis in Synthetic Chemistry

Sujoy Rana, Atanu Modak, Soham Maity, Tuhin Patra, and Debabrata Maiti

Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, India

CONTENTS

1. I. Introduction
2. II. Addition Reactions
   1. A. Cycloadditions
      1. 1. The [2 + 2] Cycloaddition
      2. 2. The [3 + 2] Cycloaddition
      3. 3. The [2 + 2 + 2] Cycloaddition
      4. 4. The [4 + 2] Cycloaddition
   2. B. Cyclopropanation
   3. C. Aziridination and Aziridine Ring-Opening Reactions
   4. D. Carbometalation of C—C Unsaturated Bond
   5. E. Michael Addition
   6. F. Barbier-Type Reaction
   7. G. Kharasch Reaction
3. III. The C—C Bond Formations VIA C—H Functionalization
   1. A. The C—H Arylation
      1. 1. Direct Arylation With Organometallic Reagents
      2. 2. Direct Arylation With Aryl Halides
   2. B. The C—C Bond Formation Via Cross-Dehydrogenative Coupling
      1. 1. The CDC Between Two sp³ C—H Bonds
      2. 2. The CDC Between sp³ and sp² C—H Bonds
      3. 3. The CDC Between sp³ and sp C—H Bonds
   3. C. The C—C Bond Formation via Cross-Decarboxylative Coupling
   4. D. The C—C Bond Formation via Alkene Insertion
   5. E. Oxidative Coupling of Two C—H Bonds
4. IV. The C—H Bond Oxidation
   1. A. Hydroxylation
   2. B. Epoxidation
   3. C. cis-Dihydroxylation
5. V. Cross-Coupling Reactions
   1. A. Alkenyl Derivatives as Coupling Partners
   2. B. Aryl Derivatives as Coupling Partners
   3. C. Alkyl Derivatives as Coupling Partners
      1. 1. Low-Valent Iron Complex in Cross-Coupling Reactions
   4. D. Acyl Derivatives as Coupling Partners
   5. E. Iron-Catalyzed C—O, C—S, and C—N Cross-Coupling Reaction
   6. F. Iron-Catalyzed Mizoraki–Heck Reaction
   7. G. Iron-Catalyzed Negishi Coupling Reaction
   8. H. Suzuki–Miyaura Coupling Reaction
   9. I. Sonogashira Reaction
   10. J. Mechanism of Cross-Coupling Reactions
   11. K. Hydrocarboxylation
   12. L. Enyne Cross-Coupling Reaction
6. VI. Direct C—N Bond Formation VIA C—H Oxidation
7. VII. Iron-Catalyzed Amination
   1. A. Allylic Aminations
   2. B. Intramolecular Allylic Amination
8. VIII. Sulfoxidations and Synthesis of Sulfoximines, Sulfimides, and Sulfoximides
   1. A. Sulfoxidation
   2. B. Synthesis of Sulfoximines, Sulfimides, and Sulfoximides
      1. 1. Mechanism
9. IX. Reduction Reactions
   1. A. Hydrosilylation of Alkenes
   2. B. Hydrosilylation of Aldehydes and Ketones
   3. C. Hydrogenation of C—C Unsaturated Bonds
   4. D. Hydrogenation of Ketones
   5. E. Hydrogenation of Imines
   6. F. Reduction of Nitroarene to Anilines
   7. G. Hydrogenation of Carbon Dioxide and Bicarbonate
   8. H. Amide Reduction
   9. I. Reductive Aminations
10. X. Trifluoromethylation
11. XI. Conclusion
12. Acknowledgments
13. Abbreviations
...

Table of contents

• Cover
• Advisory Board
• Title Page
• Copyright
• Chapter 1: Iron Catalysis in Synthetic Chemistry
• Chapter 2: A New Paradigm for Photodynamic Therapy Drug Design: Multifunctional, Supramolecular DNA Photomodification Agents Featuring Ru(II)/Os(II) Light Absorbers Coupled to Pt(II) or Rh(III) Bioactive Sites
• Chapter 3: Selective Binding of Zn2+ Complexes to Non-Canonical Thymine or Uracil in DNA or RNA
• Chapter 4: Progress Toward the Electrocatalytic Production of Liquid Fuels from Carbon Dioxide
• Chapter 5: Monomeric Dinitrosyl Iron Complexes: Synthesis and Reactivity
• Chapter 6: Interactions of Nitrosoalkanes/arenes, Nitrosamines, Nitrosothiols, and Alkyl Nitrites with Metals
• Chapter 7: Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging Oxidative Transformations
• Subject Index
• Cumulative Index
• End User License Agreement