Spin Resonance Spectroscopy
eBook - ePub

Spin Resonance Spectroscopy

Principles and applications

  1. 378 pages
  2. English
  3. ePUB (mobile friendly)
  4. Available on iOS & Android
eBook - ePub

Spin Resonance Spectroscopy

Principles and applications

About this book

Spin Resonance Spectroscopy: Principles and Applications presents the principles, recent advancements and applications of nuclear magnetic resonance (NMR) and electron paramagnetic resonance (EPR) in a single multi-disciplinary reference. Spin resonance spectroscopic techniques through NMR and EPR are widely used by chemists, physicists, biologists and medicinal chemists. This book addresses the need for new spin resonance spectroscopy content while also presenting the principles, recent advancements and applications of NMR and EPR simultaneously. Ideal for researchers and students alike, the book provides a single source of NMR and EPR applications using a dynamic, holistic and multi-disciplinary approach.- Presents a highly interdisciplinary approach by including NMR and EPR applications in chemistry, physics, biology and biotechnology- Addresses both NMR and EPR, making its concepts and applications implementable in multiple resonance environments and core scientific disciplines- Features a broad range of methods, examples and illustrations for both NMR and EPR to aid in retention and underscore key concepts

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Yes, you can access Spin Resonance Spectroscopy by Chandran Karunakaran,CHANDRAN KARUNAKARAN in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Physical & Theoretical Chemistry. We have over one million books available in our catalogue for you to explore.
Chapter One

Principles of Nuclear Magnetic Resonance and Pulsed Nuclear Magnetic Resonance

Chandran Karunakaran, Raju Rajkumar, and Murugesan Balamurugan VHNSN College (Autonomous), Virudhunagar, India

Abstract

Spin resonance spectroscopy deals with the nuclear and electron spin resonance absorptions in the radio and microwave frequencies used for investigating diamagnetic (I ≄ 1/2) and paramagnetic (S ≄ 1/2) systems, respectively. This chapter focuses on the theory of nuclear magnetic resonance (NMR), its instrumentation, and comparison with electron paramagnetic resonance spectroscopy. The parameters obtained from NMR viz., chemical shift and spin–spin splitting including their types (first and second orders), characteristics, and mechanisms (dipolar and indirect scalar coupling) are discussed. Furthermore, the classification of NMR systems including chemically and magnetically equivalent nuclei is presented. The simplification techniques for complex NMR spectra are also highlighted. It also includes the principles of pulse and Fourier transform NMR and different methods viz., free induction decay, saturation recovery, spin echo (SE), inversion recovery, and stimulated SE to investigate the relaxation process and times. The time evolution of magnetization is described by Bloch equation. The different lineshapes and factors affecting line width are also discussed.

Keywords

Chemical shift; Coupling constant; FID; Lineshape and line width; NMR spin system; Relaxation times; Spin echo

Table of contents

  1. Cover image
  2. Title page
  3. Table of Contents
  4. Copyright
  5. List of Contributors
  6. Preface
  7. Abbreviations
  8. Chapter One. Principles of Nuclear Magnetic Resonance and Pulsed Nuclear Magnetic Resonance
  9. Chapter Two. 1H and 13C Nuclear Magnetic Resonance Spectroscopy
  10. Chapter Three. Applications of Nuclear Magnetic Resonance
  11. Chapter Four. Electron Paramagnetic Resonance Spectroscopy
  12. Chapter Five. Advances in Electron Paramagnetic Resonance
  13. Chapter Six. Applications of Electron Paramagnetic Resonance
  14. Index