Handbook of Polymers
eBook - ePub

Handbook of Polymers

  1. 712 pages
  2. English
  3. ePUB (mobile friendly)
  4. Available on iOS & Android
eBook - ePub

Handbook of Polymers

About this book

Handbook of Polymers, Second Edition, presents normalized, up-to-date polymer data in a consistent and easily referenceable layout. This new edition represents an update of the available data, including new values for many commercially available products, verification of existing data, and removal of older data where it is no longer useful. The book includes data on all major polymeric materials used by the plastics industry and all branches of the chemical industry, as well as specialty polymers used in the electronics, pharmaceutical, medical, and space fields. The entire scope of the data is divided into sections to make data comparison and search easy, including synthesis, physical, mechanical, and rheological properties, chemical resistance, toxicity and environmental impact, and more. The data enables engineers and materials scientists to solve practical problems, be that in applications, research and development, or legislation. The most current grades of materials have been selected to provide readers with information that is characteristic of currently available products. - Includes practical data on the most widely used polymers for engineers and materials scientists in design, manufacture, and applications research - Presents data on polymer synthesis, properties, chemical resistance, processing, and their related environmental impacts - Provides a comprehensive update to the data, including new information and the verification of existing datasets

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Introduction

Polymers selected for this edition of the Handbook of Polymers include all major polymeric materials used by the plastics and other branches of the chemical industry as well as specialty polymers used in the electronics, pharmaceutical, medical, and space fields. Extensive information is provided on biopolymers.
The data included in the Handbook of Polymers come from open literature (published articles, conference papers, and books), literature available from manufacturers of various grades of polymers, plastics, and finished products, and patent literature. The above sources were searched, including the most recent literature. It can be seen from the references that a large portion of the data comes from information published in 2011-2016. This underscores one of the major goals of this undertaking, which is to provide readers with the most up-to-date information.
Frequently, data from different sources vary in a broad range and they have to be reconciled. In such cases, values closest to their average and values based on testing of the most current grades of materials are selected to provide readers with information which is characteristic of currently available products, focusing on the potential use of data in solving practical problems. In this process of verification many older data were rejected unless they have been confirmed by recently conducted studies.
Presentation of data for all polymers is based on a consistent pattern of data arrangement, although, depending on data availability, only data fields which contain actual values are included for each individual polymer. The entire scope of the data is divided into sections to make data comparison and search easy.
The following sections of data are included:
• General
• History
• Synthesis
• Structure
• Commercial polymers
• Physical properties
• Mechanical properties
• Chemical resistance
• Flammability
• Weather stability
• Biodegradation
• Toxicity
• Environmental impact
• Processing
• Blends
• Analysis
It can be anticipated from the above breakdown of information that the Handbook of Polymers contains information on all essential data used in practical applications, research, and legislation, providing such data are available for a particular material. In total, over 230 different types of data were searched for each individual polymer. The last number does not include special fields that might be added to characterize the performance of specialty polymers in their applications.
In most cases, the information provided is self-explanatory, considering that each data field is composed of parameter (or measured property), unit, value, and (in many cases) reference. In some cases, different values or a range of values are given. This is to indicate the fact that there is a disagreement in the published data which cannot be reconciled, or that the data falls into a broader range because various grades differ in properties. Utmost care is taken that the specified range contains grades known from published data. If there are specific grades differing in properties, a set of separate ranges is given in some cases.
After some data, information is given in parenthesis to indicate additional characteristics of tested samples. The usual convention is that the first value given is for pure or typical material, followed by its different modifications (e.g., reinforcements with different fibers or different levels of crystallinity, structure, or different conditions of sample preparation as to its temperature, state, etc.).
The range of molecular weights and related data (e.g., polymerization degree) requires additional explanation. In some cases, the number average molecular weight data do not correspond to mass average molecular data (as could be expected from a given range of polydispersities). This is because these data are given based on values found in literature without any attempts to reconcile them by means of calculation, which seems to be the correct approach because the data strictly reflect values found in the literature, not the results of any approximations which will artificially compare sets of data for materials coming from different experimental or production conditions. This is in agreement with one essential goal of this collection – authenticity of the data selected.
We hope that the results of our thorough search will be useful and that the data will be skillfully applied by users of this book for the benefit of their research and applications.

ABA acrylonitrile-butadiene-acrylate copolymer

PARAMETER UNIT VALUE REFERENCES
GENERAL
Common name acrylonitrile-butadiene-acrylate copolymer
Acronym ABA
COMMERCIAL POLYMERS
Some manufacturers Solvay
Trade names AvaSpire
PHYSICAL PROPERTIES
Density at 20°C g cm−3 1.29-1.32
Melting temperature, DSC °C 340; 340-345 (30-40% glass fiber); 340 (30% carbon fiber)
Thermal expansion coefficient, 23-80°C °C−1 0.45-...

Table of contents

  1. Cover image
  2. Title page
  3. Table of Contents
  4. Copyright
  5. Chapter 1: Introduction
  6. Chapter 2: ABA acrylonitrile-butadiene-acrylate copolymer
  7. Chapter 3: ABS poly(acrylonitrile-co-butadiene-co-styrene)
  8. Chapter 4: AK alkyd resin
  9. Chapter 5: ASA poly(acrylonitrile-co-styrene-co-acrylate)
  10. Chapter 6: BIIR bromobutyl rubber
  11. Chapter 7: BMI polybismaleimide
  12. Chapter 8: BZ polybenzoxazine
  13. Chapter 9: C cellulose
  14. Chapter 10: CA cellulose acetate
  15. Chapter 11: CAB cellulose acetate butyrate
  16. Chapter 12: CAP cellulose acetate propionate
  17. Chapter 13: CAPh cellulose acetate phthalate
  18. Chapter 14: CAR carrageenan
  19. Chapter 15: CB cellulose butyrate
  20. Chapter 16: CEC carboxylated ethylene copolymer
  21. Chapter 17: CHI chitosan
  22. Chapter 18: CIIR chlorobutyl rubber
  23. Chapter 19: CMC carboxymethyl cellulose
  24. Chapter 20: CN cellulose nitrate
  25. Chapter 21: COC cyclic olefin copolymer
  26. Chapter 22: CPE chlorinated polyethylene
  27. Chapter 23: CPVC chlorinated poly(vinyl chloride)
  28. Chapter 24: CR polychloroprene
  29. Chapter 25: CSP chlorosulfonated polyethylene
  30. Chapter 26: CTA cellulose triacetate
  31. Chapter 27: CY cyanoacrylate
  32. Chapter 28: DAP poly(diallyl phthalate)
  33. Chapter 29: E-RLPO poly(ethyl acrylate-co-methyl methacrylate-co-triammonioethyl methacrylate chloride)
  34. Chapter 30: EAA poly(ethylene-co-acrylic acid)
  35. Chapter 31: EAMM poly(ethyl acrylate-co-methyl methacrylate)
  36. Chapter 32: EBAC poly(ethylene-co-butyl acrylate)
  37. Chapter 33: EBCO ethylene-n-butyl acrylate-carbon monoxide terpolymer
  38. Chapter 34: EC ethyl cellulose
  39. Chapter 35: ECTFE poly(ethylene-co-chlorotrifl uoroethylene)
  40. Chapter 36: EEAC poly(ethylene-co-ethyl acrylate)
  41. Chapter 37: EMA poly(ethylene-co-methyl acrylate)
  42. Chapter 38: EMA-AA poly(ethylene-co-methyl acrylate-co-acrylic acid)
  43. Chapter 39: ENBA poly(ethylene-co-n-butyl acrylate)
  44. Chapter 40: EP epoxy resin
  45. Chapter 41: EPDM ethylene-propylene diene terpolymer
  46. Chapter 42: EPR ethylene-propylene rubber
  47. Chapter 43: ETFE poly(ethylene-co-tetrafl uoroethylene)
  48. Chapter 44: EVAC ethylene-vinyl acetate copolymer
  49. Chapter 45: EVOH ethylene-vinyl alcohol copolymer
  50. Chapter 46: FEP fl uorinated ethylene-propylene copolymer
  51. Chapter 47: FR furan resin
  52. Chapter 48: GEL gelatin
  53. Chapter 49: GT gum tragacanth
  54. Chapter 50: HPC hydroxypropyl cellulose
  55. Chapter 51: HDPE high density polyethylene
  56. Chapter 52: HEC hydroxyethyl cellulose
  57. Chapter 53: HPMC hydroxypropyl methylcellulose
  58. Chapter 54: HPMM poly(methacrylic acid-co-methyl methacrylate)
  59. Chapter 55: IIR isobutylene-isoprene rubber
  60. Chapter 56: LCP liquid crystalline polymers
  61. Chapter 57: LDPE low density polyethylene
  62. Chapter 58: LLDPE linear low density polyethylene
  63. Chapter 59: MABS poly(methyl methacrylate-co-butadiene-co-styrene)
  64. Chapter 60: MBS poly(styrene-co-butadiene-co-methyl methacrylate)
  65. Chapter 61: MC methylcellulose
  66. Chapter 62: MF melamine-formaldehyde resin
  67. Chapter 63: MP melamine-phenolic resin
  68. Chapter 64: NBR acrylonitrile-butadiene elastomer
  69. Chapter 65: PA-3 polyamide-3
  70. Chapter 66: PA-4,6 polyamide-4,6
  71. Chapter 67: PA-4,10 polyamide-4,10
  72. Chapter 68: PA-6 polyamide-6
  73. Chapter 69: PA-6,6 polyamide-6,6
  74. Chapter 70: PA-6,10 polyamide-6,10
  75. Chapter 71: PA-6,12 polyamide-6,12
  76. Chapter 72: PA-6,66 polyamide-6,66
  77. Chapter 73: PA-6I,6T polyamide-6I/6T
  78. Chapter 74: PA-11 polyamide-11
  79. Chapter 75: PA-12 polyamide-12
  80. Chapter 76: PAA poly(acrylic acid)
  81. Chapter 77: PAAm polyacrylamide
  82. Chapter 78: PAC polyacetylene
  83. Chapter 79: PAEK polyaryletherketone
  84. Chapter 80: PAH polyanhydride
  85. Chapter 81: PAI poly(amide imide)
  86. Chapter 82: Palg alginic acid
  87. Chapter 83: PAN polyacrylonitrile
  88. Chapter 84: PANI polyaniline
  89. Chapter 85: PAR polyarylate
  90. Chapter 86: PARA polyamide MXD6
  91. Chapter 87: PB 1,2-polybutylene
  92. Chapter 88: PBA poly(p-benzamide)
  93. Chapter 89: PBAA poly(butadiene-co-acrylonitrile-co-acrylic acid)
  94. Chapter 90: PBD, cis cis-1,4-polybutadiene
  95. Chapter 91: PBD, trans trans-1,4-polybutadiene
  96. Chapter 92: PBI polybenzimidazole
  97. Chapter 93: PBMA polybutylmethacrylate
  98. Chapter 94: PBN poly(butylene 2,6-naphthalate)
  99. Chapter 95: PBT poly(butylene terephthalate)
  100. Chapter 96: PC polycarbonate
  101. Chapter 97: PCL poly(ɛ-caprolactone)
  102. Chapter 98: PCS polycarbodihydridosilane
  103. Chapter 99: PCT poly(cyclohexylene terephthalate)
  104. Chapter 100: PCTFE polychlorotrifl uoroethylene
  105. Chapter 101: PCTG poly(ethylene-co-1,4-cyclohexylenedimethylene terephthalate)
  106. Chapter 102: PDCPD polydicyclopentadiene
  107. Chapter 103: PDL polylysine
  108. Chapter 104: PDMS polydimethylsiloxane
  109. Chapter 105: PDPD poly(dicyclopentadiene-co-p-cresol)
  110. Chapter 106: PDS polydioxanone
  111. Chapter 107: PE polyethylene
  112. Chapter 108: PEA poly(ethyl acrylate)
  113. Chapter 109: PEC poly(ester carbonate)
  114. Chapter 110: PEDOT poly(3,4-ethylenedioxythiophene)
  115. Chapter 111: PEEK polyetheretherketone
  116. Chapter 112: PEF poly(ethylene furanoate)
  117. Chapter 113: PEI poly(ether imide)
  118. Chapter 114: PEK polyetherketone
  119. Chapter 115: PEKK polyetherketoneketone
  120. Chapter 116: PEM poly(ethylene-co-methacrylic acid)
  121. Chapter 117: PEN poly(ethylene 2,6-naphthalate)
  122. Chapter 118: PEO poly(ethylene oxide)
  123. Chapter 119: PES poly(ether sulfone)
  124. Chapter 120: PET poly(ethylene terephthalate)
  125. Chapter 121: PEX silane-crosslinkable polyethylene
  126. Chapter 122: PF phenol-formaldehyde resin
  127. Chapter 123: PFA perfluoroalkoxy resin
  128. Chapter 124: PFI perfluorinated ionomer
  129. Chapter 125: PFPE perfluoropolyether
  130. Chapter 126: PGA poly(glycolic acid)
  131. Chapter 127: PHB poly(3-hydroxybutyrate)
  132. Chapter 128: PHBV poly(3-hydroxybutyrate-co-3-hydroxyvalerate)
  133. Chapter 129: PHEMA poly(2-hydroxyethyl methacrylate)
  134. Chapter 130: PHSQ polyhydridosilsesquioxane
  135. Chapter 131: PHT polyhexahydrotriazine
  136. Chapter 132: PI polyimide
  137. Chapter 133: PIB polyisobutylene
  138. Chapter 134: PIB, cis cis-polyisoprene
  139. Chapter 135: PIP, trans trans-polyisoprene
  140. Chapter 136: PK polyketone
  141. Chapter 137: PLA poly(lactic acid)
  142. Chapter 138: PLGA poly(DL-lactide-co-glycolide)
  143. Chapter 139: PLS poly(L-serine)
  144. Chapter 140: PLT poly(L-tyrosine)
  145. Chapter 141: PMA poly(methyl acrylate)
  146. Chapter 142: PMAA poly(methacrylic acid)
  147. Chapter 143: PMAN polymethacrylonitrile
  148. Chapter 144: PMFS polymethyltrifluoropropylsiloxane
  149. Chapter 145: PMMA polymethylmethacrylate
  150. Chapter 146: PMP polymethylpentene
  151. Chapter 147: PMPS polymethylphenylsilylene
  152. Chapter 148: PMS poly(p-methylstyrene)
  153. Chapter 149: PMSQ polymethylsilsesquioxane
  154. Chapter 150: PN polynorbornene
  155. Chapter 151: PNR phthalonitrile resin
  156. Chapter 152: POE very highly branched polyethylene
  157. Chapter 153: POM polyoxymethylene
  158. Chapter 154: PP polypropylene
  159. Chapter 155: PP, iso isotactic-polypropylene
  160. Chapter 156: PP, syndio syndiotactic-polypropylene
  161. Chapter 157: PPA polyphthalamide
  162. Chapter 158: PPG polypropylene glycol
  163. Chapter 159: PPMA polypropylene, maleic anhydride modified
  164. Chapter 160: PPO poly(phenylene oxide)
  165. Chapter 161: PPP poly(1,4-phenylene)
  166. Chapter 162: PPP poly(1,4-phenylene)
  167. Chapter 163: PPSE poly(trimethylsilyl phosphate)
  168. Chapter 164: PPSQ polyphenylsilsesquioxane
  169. Chapter 165: PPSU poly(phenylene sulfone)
  170. Chapter 166: PPT poly(propylene terephthalate)
  171. Chapter 167: PPTA poly(p-phenylene terephthalamide)
  172. Chapter 168: PPTI poly(m-phenylene isophthalamide)
  173. Chapter 169: PPV poly(1,4-phenylene vinylene)
  174. Chapter 170: PPX poly(p-xylylene)
  175. Chapter 171: PPy polypyrrole
  176. Chapter 172: PR proteins
  177. Chapter 173: PS polystyrene
  178. Chapter 174: PS, iso isotactic-polystyrene
  179. Chapter 175: PS, syndio syndiotactic-polystyrene
  180. Chapter 176: PSM polysilylenemethylene
  181. Chapter 177: PSMS poly(styrene-co-α-methylstyrene)
  182. Chapter 178: PSR polysulfide
  183. Chapter 179: PSU polysulfone
  184. Chapter 180: PTFE polytetrafluoroethylene
  185. Chapter 181: PTFE-AF poly(tetrafluoroethylene-co-2,2-bis(trifluoromethyl)-4,5-difluoro-1,3-dioxole)
  186. Chapter 182: PTMG poly(tetramethylene glycol)
  187. Chapter 183: PTT poly(trimethylene terephthalate)
  188. Chapter 184: PU polyurethane
  189. Chapter 185: PVAc poly(vinyl acetate)
  190. Chapter 186: PVAl poly(vinyl alcohol)
  191. Chapter 187: PVB poly(vinyl butyrate)
  192. Chapter 188: PVC poly(vinyl chloride)
  193. Chapter 189: PVCA poly(vinyl chloride-co-vinyl acetate)
  194. Chapter 190: PVDC poly(vinylidene chloride)
  195. Chapter 191: PVDF poly(vinylidene fluoride)
  196. Chapter 192: PVDF-HFP poly(vinylidene fluoride-co-hexafluoropropylene)
  197. Chapter 193: PVF poly(vinyl fluoride)
  198. Chapter 194: PVK poly(N-vinyl carbazole)
  199. Chapter 195: PVME poly(vinyl methyl ether)
  200. Chapter 196: PVP poly(N-vinyl pyrrolidone)
  201. Chapter 197: PZ polyphosphazene
  202. Chapter 198: SAN poly(styrene-co-acrylonitrile)
  203. Chapter 199: SBC styrene-butadiene block copolymer
  204. Chapter 200: SBR poly(styrene-co-butadiene)
  205. Chapter 201: SBS styrene-butadiene-styrene triblock copolymer
  206. Chapter 202: SEBS styrene-ethylene-butylene-styrene triblock copolymer
  207. Chapter 203: SIS styrene-isoprene-styrene block copolymer
  208. Chapter 204: SMA poly(styrene-co-maleic anhydride)
  209. Chapter 205: SMAA poly(styrene-co-methylmethacrylate)
  210. Chapter 206: ST starch
  211. Chapter 207: TPU thermoplastic polyurethane
  212. Chapter 208: UF urea-formaldehyde resin
  213. Chapter 209: UHMWPE ultrahigh molecular weight polyethylene
  214. Chapter 210: ULDPE ultralow density polyethylene
  215. Chapter 211: UP unsaturated polyester
  216. Chapter 212: VE vinyl ester resin
  217. Chapter 213: XG xanthan gum