1.1. Introduction
Fuels for domestic and industrial use are changing with the passage of time and have continued to do so since whale oil was first used as illuminating oil followed by kerosene as the illuminant. From that time, with the onset of the modern petroleum industry in 1856, petroleum and coal have been the dominant fuel sources and are now joined by natural gas, shale gas, oil from shale, tar sand bitumen, and oil shale (from which shale oil is produced by thermal decomposition of the kerogen) in the shaleâthese are the so-called conventional fuel sources and which will be the dominant fuel sources for the next several decades (Speight and Ozum, 2002; Hsu and Robinson, 2006; Gary et al., 2007; Speight, 2007, 2008, 2009; Bower, 2009; Wihbey, 2009; Crane et al., 2010; Levant, 2010; Speight, 2011a,b,c, 2012, 2013a,b,c, 2014a,b). All of these sources are fossil fuel sources, are nonrenewable, and cannot be replaced without invoking the concept of geological time and, therefore, sustainability of current fuel sources is open to debate (Crane et al., 2010; Zatzman, 2012).
To clarify and avoid the confusion regarding recent terminology, the term oil from shale is a petroleum-type oil than can be recovered in its natural state from shale formations, whereas shale oil is a petroleum substitute oil which does not exist in a natural state in shale and is produced by thermal decomposition of the organic material (kerogen) in oil shale. Shale oil is produced from either mined or unmined (in situ) shale (Speight and Ozum, 2002; Hsu and Robinson, 2006; Gary et al., 2007; Speight, 2013a, 2014a).
Nonconventional energy sources (also called alternative energy sources) are any sources or substances that can be used to produce fuels, other than conventional fuels. These are sources that are continuously replenished by natural processes, including biomass, hydropower, nuclear power, solar energy, and tidal energy. Examples of nonconventional fuels include biodiesel, bioalcohols (methanol, ethanol, butanol produced from biological sources), hydrogen, and fuels from other nonconventional (nonfossil fuel) sources (Speight, 2011a,b).
Furthermore, a biofuel is any as solid, liquid, or gaseous fuel consisting of, or derived from, biomass. Biomass can also be used directly for heating or powerâknown as biomass fuel. Biofuel can be produced from any carbon source that can be replenished rapidly, for example, plants. Many different plants and plant-derived materials are used for biofuel manufacture and the various technologies applied to produce biofuels hold great promise (Speight, 2008; Giampietro and Mayumi, 2009; EREC, 2010; Langeveld et al., 2010; Speight, 2011a,b).
On the other hand, there are fuels known as flexible fuels that are typically mixture of fuels such as gasoline and ethanol. Thus, a flexible-fuel vehicle (FFV) is, for example, an automobile that can alternate between two or more sources of fuel such as gasoline and ethanol mixtures. Flexible-fuel vehicles are already in production by automobile manufacturers and are engineered to run on blends of gasoline and ethanol in any percentage up to 85%. For example, E85 is a liquid fuel that is 85% v/v ethanol and 15% v/v gasolineâthe mixture can be seasonally adjusted for variations in the weather and may, at times, be less than 85% v/v ethanol. To be considered an alternative fuel vehicle (for tax incentives), the automobile or truck must be able to operate on up to 85% v/v ethanol. However, to use any ethanol blend in accordance with the specifications provided by the manufacturer, each manufacturer will, more than likely, have individual specifications. Generally, all gasoline-fueled vehicles are FFVs insofar as they are able to operate on gasoline and ethanol blends up to 10% v/v ethanolâin fact, most gasoline sold in the United States has approximately that amount of ethanol to meet c...