1.1. Crystalline Materials
Dislocations are an important class of defect in crystalline solids and so an elementary understanding of crystallinity is required before dislocations can be introduced. Metals and many important classes of non-metallic solids are crystalline, i.e. the constituent atoms are arranged in a pattern that repeats itself periodically in three dimensions. The actual arrangement of the atoms is described by the crystal structure. The crystal structures of most pure metals are relatively simple: the three most common are the body-centered cubic, face-centered cubic and close-packed hexagonal, and are described in section 1.2. In contrast, the structures of alloys and non-metallic compounds are often complex.
The arrangement of atoms in a crystal can be described with respect to a three-dimensional net formed by three sets of straight, parallel lines as in Fig. 1.1(a). The lines divide space into equal sized parallelepipeds and the points at the intersection of the lines define a space lattice. Every point of a space lattice has identical surroundings. Each parallelepiped is called a unit cell and the crystal is constructed by stacking identical unit cells face to face in perfect alignment in three dimensions. By placing a motif unit of one or more atoms at every lattice site the regular structure of a perfect crystal is obtained.
The positions of the
planes,
directions and
point sites in a lattice are described by reference to the unit cell and the three principal axes,
x,
y and
z (
Fig. 1.1(b)). The cell dimensions
OA=
a,
OB=
b and
OC=
c are the lattice parameters, and these along with the angles
,
and
completely define the size and shape of the cell. For simplicity the discussion here will be restricted to cubic and hexagonal crystal structures. In cubic crystals
a=
b=
c and
Ī±=
Ī²=
Ī³=90Ā°, and the definition of planes and directions is straightforward. In hexagonal crystals it is convenient to use a different approach, and this is described in
section 1.2.
Any plane Aā²Bā²Cā² in Fig. 1.2 can be defined by the intercepts OAā², OBā² and OCā² with the three principal axes. The usual notation (Miller indices) is to take the reciprocals of the ratios of the intercepts to the corresponding unit cell dimensions. Thus Aā²Bā²Cā² is represented by
and the numbers are then reduced to the three smallest integers in these ratios.
Thus from Fig. 1.2OAā²=2a, OBā²=3a, and OCā²=3a, the reciprocal intercepts are
and so the Miller indices of the
Aā²Bā²Cā² plane are (322). Curved brackets are used for planes. A plane with intercepts
OA,
OB, and
OC has Miller indices
or, more simply, (111). Similarly, a plane
DFBA in
Fig. 1.3 is
or (110); a plane
DEGA is
or (100); and a plane
ABā²Cā² in
Fig. 1.2 is
or (311). In determining the indices of any plane it is most convenient to identify the plane of lattice points parallel to the plane which is closest to the origin
O and intersects the principal axis close to the origin. Thus plane
Aā³
Bā²Cā² in
Fig. 1.2 is parallel to
ABC and it is clear that the indices are (111). Using this approach it will be seen that the planes
ABC,
ABE,
CEA and
CEB in
Fig. 1.3 are (111),
,
and
respectively. The minus sign above an index indicates that the plane cuts the axis on the negative side of the origin. In a cubic crystal structure, these planes constitute a group of the same crystallographic type and are described collectively by {111}.
Any direction LM in Fig. ...