Best Synthetic Methods: Acetylenes, Allenes and Cumulenes
eBook - PDF

Best Synthetic Methods: Acetylenes, Allenes and Cumulenes

  1. 502 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Best Synthetic Methods: Acetylenes, Allenes and Cumulenes

About this book

There is a vast and often bewildering array of synthetic methods and reagents available to organic chemists today. The Best Synthetic Methods series allows any scientist who is interested in the chemical transformations of molecules to choose between all the alternatives and assess their real advantages and limitations. With the emphasis on laboratory use, these volumes represent a comprehensive and practical guide to modern synthetic organic chemistry. Best Synthetic Methods: Acetylenes, Allenes and Cumulenes is the product of the author's many years practical experience and reading of the original literature. It contains a valuable distillation and critical evaluation of the Best Synthetic Methods for the formation and reaction of molecules containing carbon-carbon triple bonds or cumulative carbon-carbon double bonds. A brief review of each area is provided, but the emphasis in all cases is on describing efficient practical methods to effect the transformations described. The reader can therefore use this book to rapidly review and select the best methods of performing a synthetic conversion to create or modify a molecule containing an acetylene, allene or cumulene functionality. In addition, the documentation of a large number of experimental recipes enables the user to synthesise an unsaturated molecule without the need to access to the original literature. - Reviews and evaluates the various methods for the formation and reaction of acetylenes, cumulenes and allenes - Provides detailed practical experimental for many important reactions - General tips and analytical data are provided from the author's own extensive research in this area

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Yes, you can access Best Synthetic Methods: Acetylenes, Allenes and Cumulenes by Lambert Brandsma in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Organic Chemistry. We have over one million books available in our catalogue for you to explore.

Information

Publisher
Academic Press
Year
2003
eBook ISBN
9780080542201
Topic
Physical Sciences
Subtopic
Organic Chemistry

Table of contents

  1. Front Cover
  2. Synthesis of Acetylenes, Allenes and Cumulenes: Methods and Techniques
  3. Copyright Page
  4. Preface
  5. Contents
  6. Chapter 1. Procedures and Equipment
  7. Chapter 2. Preparation, Purification and Storage of Some Solvents and Reagents
  8. Chapter 3. Generation of Metallated Acetylenes, Allenes and Cumulenes*
  9. Chapter 4. Reactions of Metallated Acetylenes and Allenes with Alkylating Agents
  10. Chapter 5. Reactions with Aldehydes and Ketones
  11. Chapter 6. Carboxylation, Acylation and Related Reactions
  12. Chapter 7. Silylation, Stannylation and Phosphorylation
  13. Chapter 8. Sulphenylation and Related Reactions
  14. Chapter 9. Halogenation of Acetylenes
  15. Chapter 10. Acetylenes, Allenes and Cumulenes by Elimination Reactions
  16. Chapter 11. Cumulenes by Dehalogenation of Geminal Dihalogenocyclopropanes
  17. Chapter 12. Acetylenic and Allenic Derivatives by Substitution on sp- and sp2-Carbon
  18. Chapter 13. Aminoalkylation of Acetylenic Compounds
  19. Chapter 14. Cross-coupling between 1-Alkynes and 1-Bromo-1-alkynes
  20. Chapter 15. Copper Halide-Catalysed Oxidative Coupling of Acetylenes⤀
  21. Chapter 16. Transition Metals-Catalysed Couplings of Acetylenes with sp2-Halides
  22. Chapter 17. Base-Catalysed Isomerisations of Acetylenic Compounds
  23. Chapter 18. Allenic Compounds by 2,3- and 3,3-Sigmatropic Rearrangements
  24. Chapter 19. Miscellaneous Reactions of Acetylenic and Allenic Compounds
  25. Chapter 20. Transformation of Functional Groups in Acetylenic and Allenic Compounds
  26. Appendix A: 1H- and 13C-NMR Chemical Shifts of Acetylenic, Allenic and Cumulenic Compounds
  27. Appendix B: Class-Compound-Method Index
  28. Appendix C: Complementary Subject Index