Ziegler-Natta Catalysts Polymerizations
eBook - PDF

Ziegler-Natta Catalysts Polymerizations

  1. 688 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Ziegler-Natta Catalysts Polymerizations

About this book

Ziegler-Natta Catalysts and Polymerizations reviews the general aspects of Ziegler-Natta catalysts and polymerizations of olefins, dienes, and many other types of monomers. Topics covered include the physical state of the polymer during polymerization; modification of Ziegler-Natta catalysts by third components; and termination of polymer chain growth. The oxidation state of catalysts and active centers is also discussed, along with copolymerizations and block polymerizations. This book is comprised of 23 chapters and begins with an overview of Ziegler-Natta catalysts and polymerizations, their historical origins, scientific and commercial importance, and major advances in polymer science. The next chapter focuses on definitions and stereochemistry of Ziegler-Natta catalysts, together with analytical methods used to identify and quantitatively measure their structures. Some of the polymers produced commercially with Ziegler-Natta catalysts are considered. The discussion then turns to mechanisms for initiating and propagating olefins; mechanisms for stereochemical control of conjugated and nonconjugated dienes; and the basic kinetic parameters that characterize Ziegler-Natta polymerizations. This monograph is written especially for chemistry and engineering graduate students and for industrial chemists, engineers, and managers who may become involved in a Ziegler-Natta problem.

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Yes, you can access Ziegler-Natta Catalysts Polymerizations by John Jr. Boor in PDF and/or ePUB format, as well as other popular books in Technology & Engineering & Industrial & Technical Chemistry. We have over one million books available in our catalogue for you to explore.

Table of contents

  1. Front Cover
  2. Ziegler–Natta Catalysts and Polymerizations
  3. Copyright Page
  4. Table of Contents
  5. Deditation
  6. Foreword
  7. Preface
  8. John Boor
  9. CHAPTER1. HIGHLIGHTS OF ZIEGLER–NATTA CATALYSTS AND POLYMERIZATIONS
  10. CHAPTER 2. GENESIS OF ZIEGLER–NATTA CATALYSTS
  11. CHAPTER 3. DEFINITIONS, STEREOCHEMISTRY, EXPERIMENTAL METHODS, AND COMMERCIAL POLYMERS
  12. CHAPTER 4. CHEMICAL DESCRIPTION OF ZIEGLER–NATTA CATALYSTS FOR OLEFINS
  13. CHAPTER 5. THE CHEMICAL DESCRIPTION OF CATALYSTS FOR CONJUGATED DIENES
  14. CHAPTER 6. INITIAL PHYSICAL STATE OF THE CATALYST
  15. CHAPTER 7. PHYSICAL STATE OF THE POLYMER DURING POLYMERIZATION
  16. CHAPTER 8. GROWTH OF THE POLYMER PARTICLE
  17. CHAPTER 9. MODIFICATION OF ZIEGLER–NATTA CATALYSTS BY THIRD COMPONENTS
  18. CHAPTER 10. TERMINATION OF POLYMER CHAIN GROWTH
  19. CHAPTER 11. OXIDATION STATE OF CATALYSTS AND ACTIVE CENTERS
  20. CHAPTER 12. METAL ALKYL–FREE CATALYSTS
  21. CHAPTER 13. MECHANISMS FOR INITIATION AND PROPAGATION OF OLEFINS
  22. CHAPTER 14. MECHANISMS FOR INITIATION AND PROPAGATION OF DIENES
  23. CHAPTER 15. MECHANISMS FOR STEREOCHEMICAL CONTROL OF α–OLEFINS
  24. CHAPTER 16. MECHANISMS FOR STEREOCHEMICAL CONTROL OF CONJUGATED AND NONCONJUGATED DIENES
  25. CHAPTER 17. MECHANISMS FOR STEREOCHEMICAL CONTROL OF STEREOSELECTIVE AND STEREOELECTIVE ISOTACTIC PROPAGATIONS
  26. CHAPTER 18. KINETICS
  27. CHAPTER 19. POLYMERIZATION OF MONOMERS
  28. CHAPTER 20. COPOLYMERIZATIONS
  29. CHAPTER 21. BLOCK POLYMERIZATIONS
  30. CHAPTER 22. OTHER USES OF THE ZIEGLER–NATTA CATALYST
  31. CHAPTER 23. FINAL COMMENTS AND OUTLOOK
  32. Supplementary Bibliography
  33. Subject Index