eBook - PDF
Pyrolytic Methods in Organic Chemistry
Application of Flow and Flash Vacuum Pyrolytic Techniques
- 362 pages
- English
- PDF
- Available on iOS & Android
eBook - PDF
Pyrolytic Methods in Organic Chemistry
Application of Flow and Flash Vacuum Pyrolytic Techniques
About this book
Pyrolytic Methods in Organic Chemistry: Application of Flow and Flash Vacuum Pyrolytic Techniques is concerned with the use of flow pyrolysis and flash vacuum pyrolysis in preparative organic chemistry. Topics covered include pyrolytic generation and reactions of free radicals, arynes, and cyclobutadienes; elimination reactions; rearrangements of carbenes and nitrenes in the gas phase; and fragmentation of cyclic and acyclic structures. Examples of the types of reaction for which flow and flash pyrolytic methods are well suited are provided. This book is comprised of nine chapters and begins by discussing the place of flow and flash vacuum pyrolytic methods in organic chemistry. The next chapter gives an account of apparatus and experimental methods, while the remaining chapters focus on pyrolytic reactions that are grouped together according to the nature of the overall process, the formal structure of the starting material, and mechanistic type. Reactions that are formally related because they involve elimination of a small fragment molecule X-X or X-Y from a larger molecular framework are examined, along with cleavage of carbocyclic systems. The final chapter presents examples of high-temperature rearrangements, focusing on electrocyclic reactions and cycloadditions involving mainly four or six electrons; reactions that proceed through diradical intermediates; and isomerizations of heterocyclic rings. This monograph is intended mainly for practicing academic and industrial organic chemists and for advanced and graduate students.
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Yes, you can access Pyrolytic Methods in Organic Chemistry by Roger Brown in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Chemistry. We have over one million books available in our catalogue for you to explore.
Information
Table of contents
- Front Cover
- Pyrolytic Methods in Organic Chemistry: Application of Flow and Flash Vacuum Pyrolytic Techniques
- Copyright Page
- Table of Contents
- Preface
- Terminology and Conventions
- Chapter 1. The Place of Flow and Flash Vacuum Pyrolytic Methods in Organic Chemistry
- Chapter 2. Apparatus and Methods
- Chapter 3. Pyrolytic Generation and Reactions of Free Radicals, Arynes, and Cyclobutadienes
- Chapter 4. Elimination Reactions
- Chapter 5. Generation of Carbenes and Nitrenes and Their Rearrangements in the Gas Phase
- Chapter 6. Fragmentation of Cyclic Structures with Elimination of Small Molecules
- Chapter 7. Fragmentation of Acyclic Structures, and Related Cleavage of Cyclic Structures
- Chapter 8. Cleavage of Carbocyclic Systems with Related Heterocyclic Examples
- Chapter 9. Rearrangements without Fragmentation
- Index