[PDF] Catalytic Reactions The Organic Chemistry of Palladium by Peter Maitlis | Perlego
Get access to over 600,000 titles
Start your free trial today and explore our endless library.
Start free trial
Join perlego now to get access to over 600,000 books
Join perlego now to get access to over 600,000 books
Catalytic Reactions
Catalytic Reactions

Catalytic Reactions

The Organic Chemistry of Palladium
Peter Maitlis
This book is unavailable in your country
Start free trial
shareBook
Share book
pages
232 pages
language
English
format
PDF
unavailableOnMobile
Not available on the Perlego app
This book is unavailable in your country

Catalytic Reactions

The Organic Chemistry of Palladium
Peter Maitlis
Book details
Table of contents

About This Book

The Organic Chemistry of Palladium, Volume I1: Catalytic Reactions deals with organic transformations resulting from palladium complexes either stoichiometrically or catalytically. One feature of a reaction catalyzed by transition metals is the absence of evidence for the typical reactive intermediates of organic chemistry, carbanions, and carbonium ions. This lack of evidence is due to the metal acting both as a source and a sink of electrons that result in energetically unfavorable ionic intermediaries. The book explains that palladium (II) can induce C-O bond formation. These reactions involve oxidation of the organic substrate and reduces the Pd(II) to metal, and are not catalytic. Industrial applications can re-oxidize the palladium metal back to Pd(II) in situ, making the reactions catalytic. The text also discusses certain reactions that can form C-O bonds as part of an oxidative process. The book also describes significant reactions that can be catalyzed by palladium metal, such as in the hydrogenation of multiple bonds, in the carbonylation of certain olefins and acetylenes, and in the catalytic cracking of high molecular weight hydrocarbons. Organic chemists, analytical chemists, investigators, and scientists whose works involve physical or inorganic chemistry will find the book truly useful.

Read More

Information

Publisher
Elsevier Science
Year
2012
ISBN
9780323159616
Topic
Physical Sciences
Subtopic
Organic Chemistry

Table of contents