Organometallic Chemistry

Plenary Lectures Presented at the Eighth International Conference on Organometallic Chemistry, Kyoto, Japan, 12-16 September 1977

Y. Ishii, N. Hagihara

• Publisher: Pergamon
• Year: 2017
• Print ISBN: 9780080220352
• eBook ISBN: 9781483153780
• Topic: Physical Sciences
• Subtopic: Chemistry
• Index: Chemistry

Organometallic Chemistry — 8 focuses on the compositions, reactions, properties, and transformations of molecules, silicon carbon, molybdenum and tungsten compounds, palladium, and platinum. The selection first offers information on the theoretical aspects of the coordination of molecules to transition metal centers and generation and reactions of silicon-carbon double-bonded intermediates. Discussions focus on photolysis of naphthyldisilanes, alkenyldisilanes, phenylacetylene, and benzenoid aromatic derivatives of disilane. The book also considers classical and novel ylide systems in organometallic chemistry, including phosphorinanium and phospholanium ylides and organometallic compounds of double ylides. The text evaluates studies on the synthesis, mechanism, and reactivity of organo-molybdenum and tungsten compounds and enantioselective reactions through chiral metal-carbene intermediates. The manuscript also ponders on the synthesis and reactivity of carbon-bonded transition elements; neutron diffraction studies on transition metal hydride complexes; and applications of palladium in organic syntheses. The selection is an impressive reference for readers and chemists interested in organometallic chemistry.

Table of contents

• Front Cover
• Organometallic Chemistry — 8
• Copyright Page
• Table of Contents
• CHAPTER 1. THEORETICAL ASPECTS OF THE COORDINATION OF MOLECULES TO TRANSITION METAL CENTERS
• CHAPTER 2. PHOTOLYSIS OF ORGANOPOLYSILANES. GENERATION AND REACTIONS OF SILICON CARBON DOUBLE-BONDED INTERMEDIATES
• CHAPTER 3. CLASSICAL AND NOVEL YLIDE SYSTEMS IN ORGANOMETALLIC CHEMISTRY
• CHAPTER 4. STUDIES ON SYNTHESIS, MECHANISM AND REACTIVITY OF SOME ORGANO–MOLYBDENUM AND –TUNGSTEN COMPOUNDS
• CHAPTER 5. ENANTIOSELECTIVE REACTIONS THROUGH CHIRAL METAL-CARBENE INTERMEDIATES
• CHAPTER 6. ISOCYANIDE, CARBENE, AND RELATED CHEMISTRY OF PALLADIUM(II) AND PLATINUM(II)
• CHAPTER 7. SYNTHESIS AND REACTIVITY OF CARBON-BONDED TRANSITION ELEMENTS
• CHAPTER 8. NEUTRON DIFFRACTION STUDIES ON TRANSITION METAL HYDRIDE COMPLEXES
• CHAPTER 9. ORGANO TRANSITION METAL COMPOUNDS AS INTERMEDIATES IN HOMOGENEOUS CATALYTIC REACTIONS
• CHAPTER 10. NEW APPLICATIONS OF PALLADIUM IN ORGANIC SYNTHESES
• CHAPTER 11. UNUSUAL METAL ALKYLS
• CHAPTER 12. STOICHIOMETRIC VERSUS CATALYTIC USE OF COPPER(I) SALTS IN THE SYNTHETIC USE OF MAIN GROUP ORGANOMETALLICS
• CHAPTER 13. ON THE MECHANISMS OP SUBSTITUTION REACTIONS OF ORGANOMETALLIC COMPOUNDS OP NONTRANSITION METALS
• CHAPTER 14. ACTIVATION OP ALKANES BY TRANSITION METAL COMPLEXES
• CHAPTER 15. NEW TRENDS IN THE CHEMISTRY OF ORGANOMETALLOPORPHYRINS