Theory and Structure of Complex Compounds

Papers Presented at the Symposium Held in Wroc?aw, Poland, 15–19 June 1962

B. Jeżowska-Trzebiatowska

• Publisher: Pergamon
• Year: 2013
• Print ISBN: 9781483228419
• eBook ISBN: 9781483280950
• Topic: Ciencias físicas
• Subtopic: Química

Theory and Structure of Complex Compounds presents the development of the chemistry of complex compounds. This book discusses the various applications of complex compounds in the laboratories and industry, particularly for preparation of reactor materials, for identification of chemical elements, and extraction of rare elements. Organized into 88 chapters, this book begins with an overview of the essential role that oxygen plays in chemical compounds, particularly in complex compounds. This text then examines the redox potentials for the manganese hematoporphyrin in a water solution. Other chapters consider the results of applying the treatment to the hexacarbonyls of chromium, tungsten, and molybdenum. This book discusses as well the optical rotatory dispersion of asymmetric organic and inorganic compounds. The final chapter deals with the general equation allowing determination of the equilibrium constants of the complex formation reaction from spectro-photometric measurements. This book is a valuable resource for chemists, physicists, scientists, and mathematicians.

Table of contents

• Front Cover
• Theory and Structure of Complex Compounds
• Copyright Page
• Table of Contents
• PREFACE
• CHAPTER 1. THE ROLE OF OXYGEN IN COORDINATION COMPOUNDS
• CHAPTER 2. CHEMISTRY AND PHOTOCHEMISTRY OF IRON AND MANGANESE PORPHYRINS
• CHAPTER 3. О ФОРМИАТАХ И АЦЕТАТАХ РОДИЯ
• CHAPTER 4. ZUR STRUKTUR DER POLYMEREN FLUOROARSENATE
• CHAPTER 5. NATURE OF BONDING IN METAL CARBONYLS AS DETERMINED FROM THEIR VIBRATIONAL SPECTRA
• CHAPTER 6. SPECTRES DE VIBRATION ET STRUCTURE DE NITRITES COMPLEXES
• CHAPTER 7. SOME FACTORS INFLUENCING THE OPTICAL ROTATORY DISPERSION OF ASYMMETRIC COMPLEX INORGANIC COMPOUNDS
• CHAPTER 8. RECENT STUDIES ON THE KINETICS AND MECHANISMS OF SOME SUBSTITUTION REACTIONS OF METAL COMPLEXES
• CHAPTER 9. ÜBER DIE KOORDINATIONSEIGENSCHAFTEN DER MOLYBDÄN- UND WOLFRAMATOME
• CHAPTER 10. COORDINATION POLYMERIZATION IN METAL ALKOXIDES
• CHAPTER 11. CONFORMATION INSTABILITY OF NON-CUBO-SYMMETRIC INORGANIC COMPOUNDS IN DEGENERATE ELECTRONIC STATES
• CHAPTER 12. НЕКОТОРЫЕ РЕЗУЛЬТАТЫ НОВЫХ РЕНТГЕНОСТРУКТУРНЫХ ИССЛЕДОВАНИЙ КОМПЛЕКСНЫХ СОЕДИНЕНИЙ ПЕРЕХОДНЫХ МЕТАЛЛОВ
• CHAPTER 13. COMPLEXES DU TELLURE ET LEUR UTILISATION
• CHAPTER 14. ÜBER EINIGE KOMPLEXVERBINDUNGEN IN LÖSUNGEN
• CHAPTER 15. LICHTABSORPTIONSEIGENSCHAFTEN UND MAGNETISCHE MOMENTE VON OKTAEDRISCHEN KOMPLEXVERBINDUNGEN DES III-WERTIGEN TITANS
• CHAPTER 16. ELEKTRONENSTRUKTUR DER CHROMHEXAKARBONYL-MOLEKÜLE
• CHAPTER 17. THEORY OF THE MXk q~ IONS AND ITS APPLICATION TO [Mo(CN)8]4- AND [Mo(CN)8(NH3)2]4-
• CHAPTER 18. THE PROPERTIES OF SOLID PHOTOPRODUCTS OF OCTACYANIDES OF MOLYBDENUM(IV) AND OF TUNGSTEN(IV)
• CHAPTER 19. STABILITY, SPECTRA AND STRUCTURE OF IRON-a-DI-IMINE COMPLEXES
• CHAPTER 20. SPECTRA AND STRUCTURE OF THIOCYANATE COMPLEXES
• CHAPTER 21. ACID-BASE COMPLEXES AND FINE STRUCTURE OF THE OH STRETCHING VIBRATION BAND IN THE HYDROGEN BONDING
• CHAPTER 22. ON THE THEORY OF SPECTROSCOPY OF URANYL COMPOUNDS IN SOLUTIONS
• CHAPTER 23. ÜBER DIE RAUMSTRUKTUR DER URANYLKOMPLEXE
• CHAPTER 24. THE EFFECTS OF MEDIUM AND LIGAND EXCHANGE ON THE ABSORPTION SPECTRUM OF URANYL ION IN SOLUTIONS
• CHAPTER 25. ANHYDROUS URANYL SALTS IN ORGANIC SOLVENTS
• CHAPTER 26. СТРУКТУРА КОМПЛЕКСНЫХ СОЕДИНЕНИЙ УРАНИЛА С НЕКОТОРЫМИ β-ДИКЕТОНАМИ
• CHAPTER 27. STUDIES ON THE ABSORPTION SPECTRA OF THE U3+ ION
• CHAPTER 28. ДИПОЛЬНЫЕ МОМЕНТЫ КОМПЛЕКСОВ НИТРАТОВ НЕКОТОРЫХ ТЯЖЕЛЫХ ЭЛЕМЕНТОВ С ТРИБУТИЛФОСФАТОМ
• CHAPTER 29. APPLICATION OF M. O. METHOD FOR THE EXPLANATION OF DIAMAGNETISM OF BINUCLEAR RHENIUM(IV) COMPLEXES
• CHAPTER 30. ÜBER DIE DIAMAGNETISCHEN OXOHALOGENORHENATE(V)
• CHAPTER 31. THE MAGNETIC PROPERTIES OF "ADDITION" COMPOUNDS OF CHROMYL CHLORIDE WITH HYDROCARBONS
• CHAPTER 32. THE MAGNETIC PROPERTIES OF URANIUM(IV) COMPOUNDS
• CHAPTER 33. MAGNETISCHE MESSUNGEN MIT HILFE DES SCHWEBUNGSVERFAHRENS
• CHAPTER 34. STRUCTURE INVESTIGATION OF METAL-D1PHENYLCARBAZONE COMPLEXES BY INFRARED SPECTROSCOPY
• CHAPTER 35. COMPLEX SALTS OF TETRAZOLIUM ION WITH IONS OF TETRACHLOROGALLIC, INDIC, THALLIC AND CHLORO-ACIDS OF OTHER METALS
• CHAPTER 36. A SERIES OF DERIVATIVES IN THE GROUP OF OXTME-CYANIDES OF MOLYBDENUM
• CHAPTER 37. CARBONATE COMPLEXES OF THE LIGHTER LANTHANIDES
• CHAPTER 38. ZUR KOMPLEXCHEMIE DER o-CYCLOHEXYLIMINODIESSIGSÄUREfl) UND DER o-HYDROXYANILINDIESSIGSÄURE(II)
• CHAPTER 39. ZUR KENNTNIS DER CLATHRATE DER Me(4-ÄTHYLPYRIDIN)4(SCN)2-KOMPLEXE MIT Q-AROMATEN
• CHAPTER 40. ORGANOMETALLIC STUDIES, VII* THE RESOLUTION ON AN ARENECHROMIUM TRICARBONYL RACEMIC MIXTURE
• CHAPTER 41. THE ELECTRON SPIN RESONANCE AS PROOF OF ELECTRONIC STRUCTURE OF BINUCLEAR CHROMIUM(III) COMPLEXES
• CHAPTER 42. ON SOME PROPERTIES OF [Mn(CN)5NO]q IONS
• CHAPTER 43. INVESTCGATIONS ON CYANONITROSYL COMPLEXES OF FIRST TRANSITION METAL SERIES BY RADIOISOTOPIC EXCHANGE METHOD
• CHAPTER 44. THE CHEMICAL BOND AND ELECTRONIC STRUCTURE OF OXALATORHENATE(IV) BY RADIOISOTOPIC EXCHANGE METHOD
• CHAPTER 45. RÖNTGENSPEKTROSKOPISCHE UNTERSUCHUNGEN AN KOMPLEXVERBINDUNGEN DER ÜBERGANGSELEMENTE
• CHAPTER 46. THE CRYSTAL STRUCTURE OF COPPER TETRATfflOCYANATOMERCURATE Cu[Hg(SCN)4]
• CHAPTER 47. APPLICATION OF THE MÖSSBAUER EFFECT FOR INVESTIGATION OF CRYSTALLINE IRON COMPLEX COMPOUNDS
• CHAPTER 48. RELATION BETWEEN COORDINATION NUMBER AND DISTRIBUTION OF PROTONS
• CHAPTER 49. ПОЛУЧЕНИЕ КОМПЛЕКСОВ Tc(IV) С ИСПОЛЬЗОВАНИЕМ Re(IV) В КАЧЕСТВЕ НОСИТЕЛЯ
• CHAPTER 50. DAS KOMPLEXCHEMISCHE VERHALTEN DES ADENINS GEGENÜBER KUPFER(II)
• CHAPTER 51. THE THREE-DIMENSIONAL REFINEMENT OF THE STRUCTURE OF AIF3 THE CRYSTAL CHEMISTRY OF THE COMPLEXES OF THE TYPE MF3
• CHAPTER 52. EFFECT OF FLUORIDE ION ON THE ACTIVATION OF MOLECULAR HYDROGEN BY SILVER(I)
• CHAPTER 53. COMPOSÉS DE COORDINATION DE QUELQUES MÉTAUX DU VIII-ÈME GROUPE
• CHAPTER 54. ÉQUILIBRE D'EXTRACTION ET RÉACTIONS CHIMIQUES EN SOLVANTS PEU IONISANTS
• CHAPTER 55. BESTIMMUNG VON KOMPLEXZUSAMMENSETZUNGEN IN WÄßRIGER LÖSUNG DURCH AMINEXTRAKTION
• CHAPTER 57. UNTERSUCHUNGEN ÜBER DEN EXTRAKTIONSMECHANISMUS BEI DER DffiUTYLPHOSPHORSÄUREEXTRAKTION VON ZIRKONIUM UND NIOB
• CHAPTER 58. EXTRACTION STUDIES ON THE INTERACTION BETWEEN GeCl4 MOLECULES AND ORGANIC DILUENT
• CHAPTER 59. ВЛИЯНИЕ НИТРАТНОЙ ГРУППЫ КАК АДДЕНДА НА КИНЕТИЧЕСКУЮ УСТОЙЧИВОСТЬ КОМПЛЕК-СОВ ДВУХВАЛЕНТНОЙ МЕДИ СО СВЯЗЬЮ Сип-С1 В АЦЕТОНЕ
• CHAPTER 60. CONDITION DE LA FORMATION ET STABILITÉ DE COMPLEXES POLYSUBSTITUÉS
• CHAPTER 61. REFRACTOMETRIC METHOD OF DETERMINATION OF THE INSTABILITY CONSTANT OF COMPLEX COMPOUNDS
• CHAPTER 62. THE INFLUENCE OF THE COMPONENT ELECTRONEGATIVITIES ON THE VALUE OF THE INSTABILITY CONSTANT OF COMPLEX COMPOUNDS
• CHAPTER 63. DETÉRMINATION DE LA FORMATION DE COMPLEXES POLISUBSTITUÉS A L'AIDE DE LA МÉТНООЕ DE LA SURFACE POTENTIOMÉTRIQUE
• CHAPTER 64. THE INFLUENCE OF THE OXIDATION-REDUCTION POTENTIAL OF A HALOGENO-COMPLEX COMPONENT ON THE INSTABILITY CONSTANT
• CHAPTER 65. PAPER IONOPHORESIS OF FERRIC THIOCYANATE COMPLEXES
• CHAPTER 66. SOME INFLUENCES DETERMINING COORDINATION NUMBER OF CATIONS*
• CHAPTER 67. ON THE FORMATION OF TETRAHEDRAL COBALT(II) COMPLEXES IN SOLUTIONS
• CHAPTER 68. SPECTROPHOTOMETRIC METHODS USED IN THE INVESTIGATION OF SEVERAL COMPLEXES IN SOLUTIONS
• CHAPTER 69. STUDIES ON MIXED MERCURIC TfflOCYANATESULPHITE COMPLEXES
• CHAPTER 70. Cr(III) AMMINES. THEIR THERMODYNAMIC STABILITY AND THEIR ROBUSTNESS
• CHAPTER 71. MECHANISMS OF ONE-ELECTRON REDOX REACTIONS INVOLVING DESTRUCTION OF THE MO2+ STRUCTURE*
• CHAPTER 72. HYDROLYSIS OF V3+ ION IN NaCl MEDIUM
• CHAPTER 73. COMPLEXES OF CHROMIUM(III) WITH DL-a-ALANINE
• CHAPTER 74. POTENTIOMETRIC INVESTIGATION OF METAL–TRIS–(HYDROXYMETHYL)–AMINOMETHANE COMPLEXES
• CHAPTER 75. POLAROGRAPHIC PROPERTIES OF AQUEOUS SOLUTIONS OF MOLYBDOSILICIC ACIDS
• CHAPTER 76. POLAROGRAPHISCHES VERHALTEN DER cis-UND trans-DICHLORO-bis-ÄTHYLENDIAMIN-Co(III)-LÖSUNGEN
• CHAPTER 77. EVALUATION OF STABILITY CONSTANTS OF COMPLEXES ON THE BASIS OF POLAROGRAPHIC DATA ON IRREVERSIBLE ELECTRODE REACTIONS
• CHAPTER 78. WEITERE UNTERSUCHUNGEN ZUM ALKALISCHEN PERMANGANATZERFALL
• CHAPTER 79. SOME NEW ASPECTS OF THE REDUCTION MECHANISM OF MANGANESE OXYANIONS
• CHAPTER 80. TRANSFER OF OXYGEN BY MANGANESE(II) PHTHALOCYANINE
• CHAPTER 81. OBSERVATIONS ON THE REACTION BETWEEN U(IV) AND VARIOUS HALOGENATES
• CHAPTER 82. FORMATION OF ION COMPLEXES OF URANIUM(IV) CHLORIDE IN A MOLTEN LiCl-KCl EUTECTIC MIXTURE
• CHAPTER 83. EINE DIELEKTRISCHE METHODE ZUM STUDIUM VON KOMPLEXEN DES TRIBUTYLPHOSPHATS IN VERDÜNNTEN ORGANISCHEN LÖSUNGEN
• CHAPTER 84. DETERMINATION OF THE PROTONATION CONSTANTS OF MONOMOLYBDIC ACID BY ELECTROMIGRATION MEASUREMENTS
• CHAPTER 85. INVESTIGATION ON LIGAND EXCHANGE IN COMPLEX COMPOUNDS OF Cr(III) BY MEANS OF VOLTAGE SWEEP CHRONOAMPEROMETRY
• CHAPTER 86. DIE ROLLE DER METALLKATIONEN BEIM POLYPHOSPHATABBAU IN WÄSSERIGER LÖSUNG
• CHAPTER 87. DETERMINATION OF RELATIVE STABILITY OF ZINC, CADMIUM, AND NICKEL COMPLEXES WITH TARTARIC ACID BY ELECTROCHROMATOGRAPHIC METHOD
• CHAPTER 88. ZUR THERMODYNAMIK DER CHARGE-TRANSFERKOMPLEXE