Gas Phase Metal Reactions

A. Fontijn

• Publisher: North Holland
• Year: 2017
• Print ISBN:
  9780444890702
• eBook ISBN:
  9781483291215
• Topic: Physical Sciences
• Subtopic: Atomic & Molecular Physics

The book brings together, for the first time, all aspects of reactions of metallic species in the gas phase and gives an up-to-date overview of the field. Reactions covered include those of atomic, other free radical and transient neutral species, as well as ions. Experimental and theoretical work is reviewed and the efforts to establish a closer link between these approaches are discussed. The field is mainly approached from a fundamental point-of-view, but the applied problems which have helped stimulate the interest are pointed out and form the major subject of the final chapters. These emphasize the competition between purely gas-phase and gas-surface reactions.

Table of contents

• Front Cover
• Gas-Phase Metal Reactions
• Copyright Page
• Table of Contents
• Preface
• Chapter 1. Introduction and Overview
• Chapter 2. Chemical Kinetics and Dynamics of the Mesospheric Sodium Nightglow
• Chapter 3. A Comparison between the Oxidation Reactions of the Alkali and Alkaline Earth Atoms
• Chapter 4. Kinetics of the Molecular Oxygen Reactions with Sodium, Magnesium and Copper Atoms
• Chapter 5. Kinetic Studies of Boron and Aluminum Species
• Chapter 6. Homogeneous Kinetics of Metal Species over Wide Temperature Ranges: Techniques, Measurements, and Correlations
• Chapter 7. Reactions of Group III Metal Atom with Ethylene and Carbon Dioxide Molecules: A Matrix Isolation Study
• Chapter 8. Reactions of Boron and Aluminum Atoms with Small Molecules
• Chapter 9. Ab Initio MO Calculations of the Thermochemistry of BX, A1X, OBX and OA1X (X = 0, F, C1)
• Chapter 10. Reactive Collisions of AI, Mg, C and Si a toms
• Chapter 11. Cooperative Effects in Ligand Binding to Metal Atoms: the Bonding in M(CO)2, M = Be, Al, and Ga, and in Be2(CO)4, and Be(C2H4)(CO)n, n = 0-2
• Chapter 12. Association Reactions of Transition Metal Atoms with Simple Molecules near Room Temperature
• Chapter 13. Reactions of Gas Phase Transition Metal Atoms with Small Hydrocarbons
• Chapter 14. The Bonding in Metal Ion Systems with Multiple Ligands
• Chapter 15. Comparison of Main Group and Transition Metal Ion Chemistry
• Chapter 16. Reaction Dynamics of Ground State and Electronically Excited Barium Atoms
• Chapter 17. Effects of Electronic Excitation and Dimerization of Metals on Product State Distributions
• Chapter 18. State-to-State Dynamics for the Reactions of Metastable Cu Atoms with F2, CI2, and Br2
• Chapter 19. The Interactions of Metal Atoms with Xe, CH4 and H2: Half-Collision Studies
• Chapter 20. Harpooning Reactions of Excited Rare Gas Atoms
• Chapter 21. Studies of Some Gas-Phase Metal Oxidation Reactions by Photoelectron and Chemielectron Spectroscopy
• Chapter 22. Metal Ion Chemistry in Flames
• Chapter 23. The Flame Chemistry of Alkali and Alkaline Earth Metals
• Chapter 24. Toward the Modeling of the Oxidation of Small Metal and Metalloid Molecules
• Chapter 25. Oxidation Reactions of Metal and Semi-Metal Cluster Ions
• Chapter 26. Competition B etween Homogeneous and Heterogeneous Reactions in Metal Vapor Oxidation
• Chapter 27. Kinetics of High Temperature, Hydrocarbon Assisted Boron Combustion
• Chapter 28. Reactions of Metal Species in Dry Etching and Chemical Vapor Deposition