Novel N-Heterocyclic Carbene Ligands and their Metal Complexes
eBook - PDF

Novel N-Heterocyclic Carbene Ligands and their Metal Complexes

,
  1. 198 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Novel N-Heterocyclic Carbene Ligands and their Metal Complexes

,

About this book

N-heterocyclic carbenes (NHCs) have found robust development and were widely used as ubiquitous ligands for organometallic complexes in the past two decades. Besides the most popular Arduengo carbenes, i.e. imidazol-2-ylidene and its analogues, novel carbenes derived from N-heterocycles other than imidazole have lately attracted increasing attention. In this work, metal complexes with novel N-heterocyclic carbene ligands, such as imidazol-4/5-ylidene, pyridazin-4-ylidene, and N-metallated N-heterocyclic carbene have been synthesized and characterized. In addition, inspired by a recent discovery that a carbon atom was chelated by NHC ligands to form carbodicarbene, efforts to synthesize a novel indene-derived carbene, in which NHC ligands coordinate to carbon atoms adjacent to the carbenic carbon atom, have been carried out.

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Information

Publisher
Cuvillier Verlag
Year
2015
Print ISBN
9783954049998
eBook ISBN
9783736949997
Edition
1

Table of contents

  1. Acknowledgement
  2. TABLE OF CONTENT
  3. CHAPTER 1. Introduction
  4. CHAPTER 2. Pyridazine Derived N-Heterocyclic Carbene Palladium Complexes
  5. CHAPTER 3. Pyrazole Bridged bis(NHC) Ligands and their Dinuclear Palladium Complexes
  6. CHAPTER 4. N-Metallated N-Heterocyclic Carbene Ruthenium Complexes
  7. CHAPTER 5. Synthesis of Novel Indene Derived Carbene Ligands
  8. CHAPTER 6. Experimental Section
  9. References
  10. Appendix