Enantioselektive Synthese von dimeren Tetrahydroxanthenonen zum Aufbau der Dicerandrole und Phomoxanthone
eBook - PDF

Enantioselektive Synthese von dimeren Tetrahydroxanthenonen zum Aufbau der Dicerandrole und Phomoxanthone

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  1. 230 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Enantioselektive Synthese von dimeren Tetrahydroxanthenonen zum Aufbau der Dicerandrole und Phomoxanthone

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About this book

Die vorliegende Arbeit beschreibt die Entwicklung eines stereoselektiven Zugangs zu hoch funktionalisierten dimeren Tetrahydroxanthenonen. Hierbei spielen die Anwendung einer enantioselektiven Palladium katalysierten Wacker Oxidation und einer diastereoselektiven Sharpless-Bishydroxylierung eine zentrale Rolle bei dem Aufbau der Tetrahydroxanthenonstruktur. Das Tetrahydroxanthenon System stellt das GrundgerĂŒst einer Vielzahl komplexer Naturstoffe mit hoher struktureller DiversitĂ€t dar, welche eine interessante, breitgefĂ€cherte biologische AktivitĂ€t aufweisen wie zum Beispiel die Dicerandrole und Phomoxanthone. ZusĂ€tzlich wird in dieser Arbeit ein Zugang zu Derivaten des Hsp-47 Inhibitors dargestellt, welche anschließend in Kooperation mit der pharmakologischen Abteilung der UniversitĂ€tsmedizin Göttingen auf ihre FĂ€higkeit untersucht werden, die Entwicklung von Herzmuskelzellen zu beeinflussen.

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Information

Publisher
Cuvillier Verlag
Year
2016
Print ISBN
9783736993341
eBook ISBN
9783736983342
Edition
1

Table of contents

  1. Inhaltsverzeichnis
  2. A. Allgemeiner Teil
  3. B. Ergebnisse & Diskussion
  4. C. Zusammenfassung und Ausblick
  5. D. Experimeteller Teil
  6. E. Anhang