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Destruction of Hazardous Chemicals in the Laboratory
About this book
Destruction of Hazardous Chemicals in the Laboratory
Single volume reference providing procedural information for the destruction of a wide variety of hazardous chemicals
Destruction of Hazardous Chemicals in the Laboratory is a practical reference that describes procedures for the destruction of a comprehensive list of hazardous chemicals and provides general methods for the destruction of hazardous chemicals in the laboratory without the need for exotic reagents and equipment.
Unlike most other sources on this subject, detailed reaction parameters are provided to readers. These details will help the reader decide if a procedure will be appropriate. To further aid in reader comprehension, numerous tables throughout the book allow for ready comparison of procedures.
Destruction of Hazardous Chemicals in the Laboratory also describes the critical aspects of various protocols (e.g., UV lamp type and rate of ozone flow).
The updated fourth edition Includes an updated survey of the literature from 2012-2021 and features data mined from 1, 500 papers. It also describes recent examples of methods that are generally applicable to organic compounds and greatly expands the section on methods for the destruction of pharmaceuticals in the laboratory.
In this book, readers can expect to find detailed information on:
- Specific methods for the destruction of hazardous chemicals in the laboratory, such as aflatoxins, butyllithium, complex metal hydrides, ethidium bromide, MPTP, nitrosamines, and polycyclic aromatic hydrocarbons
- Methods for the destruction of pharmaceuticals in the laboratory, such as those using ozone, persulfate, and potassium permanganate as well as photolytic degradation procedures
- Procedures for drying organic solvents
- A discussion of the issues concerning nitrosamine formation during the destruction process, particularly when sodium hypochlorite is used
- A variety of indexes, including a general index, cross index of pharmaceuticals and destruction procedures, cross index of dyes and destruction procedures, and cross index of names for dyes and biological stains
Destruction of Hazardous Chemicals in the Laboratory is of immense value to researchers in the laboratory by enabling them to quickly and efficiently get rid of residual amounts of hazardous chemicals when a series of experiments has ended. The procedures in the text can also be incorporated into laboratory protocols.
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Information
Table of contents
- Cover
- Title Page
- Copyright
- Contents
- PREFACE
- INTRODUCTION
- SAFETY CONSIDERATIONS
- SPECIFIC METHODS FOR THE DESTRUCTION OF HAZARDOUS CHEMICALS IN THE LABORATORY
- Acetonitrile
- Acid Halides and Anhydrides
- Aflatoxins
- Alkali and Alkaline Earth Metals
- Alkali Metal Alkoxides
- Anatoxin-A
- Aromatic Amines
- Arsenic
- Azides
- Azo and Azoxy Compounds and Tetrazenes
- Boron Trifluoride and Inorganic Fluorides
- Botulinum Toxins
- Brevetoxins
- Butyllithium
- Calcium Carbide
- Carbamic Acid Esters
- Carbofuran
- Chloromethylsilanes and Silicon Tetrachloride
- N-Chlorosuccinimide and Chloramine-T
- Chlorosulfonic Acid
- Chromium(VI)
- Citrinin
- Complex Metal Hydrides
- Cyanides and Cyanogen Bromide
- Cylindrospermopsin
- Diisopropyl Fluorophosphate
- Dimethyl Sulfate and Related Compounds
- Dyes And Biological Stains
- Ethidium Bromide
- Haloethers
- Halogenated Compounds
- Halogens
- Heavy Metals
- Hexamethylphosphoramide
- Hydrazines
- Hypochlorites
- Mercury
- 2-Methylaziridine
- 1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP)
- Microcystins
- 4-Nitrobiphenyl
- 3-Nitrofluoranthene and 3-Aminofluoranthene
- Nitrogen Tetroxide
- N-Nitroso Compounds: Nitrosamides
- N-Nitroso Compounds: Nitrosamines
- Ochratoxin A
- Okadaic Acid
- Organic nitriles
- Osmium tetroxide
- Palytoxin
- Patulin
- Peracids
- Perchlorates
- Peroxides and Hydroperoxides
- Phenol
- Phosgene
- Phosphorus and Phosphorus Pentoxide
- Picric Acid
- Polycyclic Aromatic Hydrocarbons
- Polycyclic Heterocyclic Hydrocarbons
- Potassium Permanganate
- β-Propiolactone
- Protease Inhibitors
- Ricin
- Saxitoxin
- Selenium Compounds
- Sodium Amide
- Sterigmatocystin
- Sulfonyl Fluoride Enzyme Inhibitors
- Sulfur-Containing Compounds
- T-2 Toxin and Other Tricothecenes
- Tetrodotoxin
- Triacetone Triperoxide
- Uranyl Compounds
- DESTRUCTION OF PHARMACEUTICALS
- General Considerations
- Potassium Permanganate
- Nickel–Aluminum Alloy Reduction
- Fenton Reaction
- Hydrogen Peroxide
- Ozone
- Ferrate
- Persulfate
- Hydrogen Peroxide and Horseradish Peroxidase
- Specific Degradation Procedures for ß-Lactams
- Decontamination of Aqueous Solutions
- Miscellaneous Chemical Degradation Procedures
- General Considerations for Photolytic Procedures
- Photolysis Without Added Reactants (UV Only)
- Photolysis with Hydrogen Peroxide (UV/H2O2)
- Photo-Fenton Reaction
- Photolysis with Titanium Dioxide (UV/TiO2)
- Photolysis with Zinc Oxide (UV/ZnO)
- Photolysis with Ozone (UV/O3)
- Photolysis with Persulfate (UV/Persulfate)
- Photolysis with Chlorine (UV/Cl2)
- Miscellaneous Photolytic Procedures (UV/Miscellaneous)
- PROCEDURES CLASSIFIED BY METHOD
- General Considerations
- Potassium Permanganate
- Fenton Reaction
- Ozone
- Persulfate
- Miscellaneous Procedures
- Photolysis Without Added Reactants (UV only)
- Photolysis with Hydrogen Peroxide (UV/H2O2)
- Photo-Fenton Reaction
- Photolysis with Titanium Dioxide (UV/TiO2)
- Photolysis with Zinc Oxide (UV/ZnO)}
- Photolysis with Ozone (UV/O3)
- Photolysis with Persulfate (UV/Persulfate)
- Photolysis with Chlorine (UV/Cl2)}
- Biologicals
- APPENDIXES
- Appendix I
- Appendix II
- CROSS-INDEX OF NAMES FOR DYES AND BIOLOGICAL STAINS
- CROSS-INDEX OF METHODS USED FOR SPECIFIC DYES AND BIOLOGICAL STAINS
- CROSS-INDEX OF METHODS USED FOR PHARMACEUTICALS
- Name Index
- EULA