Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells
eBook - PDF

Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells

  1. 174 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells

About this book

Lithium (Li) deposition is a problem in Li batteries (LB) - both Li metal (LMB) and Li-ion (LIB) batteries - which limits their performance in terms of power and energy density. Two trends can be identified in the advancement of LBs concerning the problem of Li deposition: optimization of the existing system (the state-of-the-art LIBs) and further development of cell components such as electrolytes. This work addresses both approaches.In the first part, this study investigates Li deposition in LMB and LIBs. A novel method to study the Li-based transport mechanisms in LIBs is introduced. Later the kinetic deviations between anode and cathode as a consequence of aging and the relation of these deviations to the occurrence of Li-plating are discussed.In the second part, the applicability of PEO-based solid polymer electrolytes for LMBs to overcome the Li plating issue is investigated. The introduction of various interfacial interlayers at the cathode/electrolyte interphase was studied to improve the electrochemical stability of the cells. Cells with an in-situ electro-deposited interlayer showed the best cyclability.

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Yes, you can access Study of lithium deposition and applicability of solid polymer electrolytes in lithium cells by Momeni Boroujeni, Sanaz in PDF and/or ePUB format. We have over one million books available in our catalogue for you to explore.

Information

Publisher
Cuvillier Verlag
Year
2022
Print ISBN
9783736977099
eBook ISBN
9783736967090
Edition
1

Table of contents

  1. Zusammenfassung
  2. Abstract
  3. Chapter 1 Introduction
  4. 1.1 Motivation
  5. 1.2 Structure of this work
  6. Chapter 2 Theoretical and experimentalbackground
  7. 2.1 Electrochemical cells
  8. 2.2 Lithium ion battery
  9. 2.3 Lithium metal battery
  10. 2.4 Solid polymer electrolytes
  11. 2.5 Instrumentation and techniques
  12. Chapter 3 Lithium deposition in Li-ion andLi-metal cells
  13. 3.1 Kinetics study to predict Li plating in a Li-ioncell
  14. 3.2 Inuence of temperature and electrolyte onLi deposition
  15. Chapter 4 Solid polymer electrolytes
  16. 4.1 Manufacturing of the PEO solid electrolyte
  17. 4.2 Manufacturing of the cathode
  18. 4.3 Passivation layers
  19. 4.4 Cell assembly
  20. 4.5 Electro and physiochemical characterization
  21. Chapter 5 Result and discussion on lithiumdeposition study in Li-ion andLi-metal cells
  22. 5.1 Kinetics study to predict Li plating
  23. 5.2 Inuence of temperature and electrolyte onLi deposition
  24. Chapter 6 Investigation on PEO-based SPEs
  25. 6.1 PEO/LiTFSI membranes
  26. 6.2 PEO/LiTFSI/passive-ceramics membranes
  27. 6.3 Stability versus NMC cathode
  28. 6.4 Coulombic effciency
  29. 6.5 Discussion and conclusion
  30. Chapter 7 Conclusion
  31. List of Tables
  32. List of Figures
  33. Bibliography
  34. Publications
  35. Aknowledgment