Applications of Group Theory to Atoms, Molecules, and Solids

Thomas Wolfram, Şinasi Ellialtıoğlu

• Publisher: Cambridge University Press
• Year: 2014
• Print ISBN: 9781107028524
• eBook ISBN: 9781107454088
• Topic: Physical Sciences
• Subtopic: Mathematical & Computational Physics

The majority of all knowledge concerning atoms, molecules, and solids has been derived from applications of group theory. Taking a unique, applications-oriented approach, this book gives readers the tools needed to analyze any atomic, molecular, or crystalline solid system. Using a clearly defined, eight-step program, this book helps readers to understand the power of group theory, what information can be obtained from it, and how to obtain it. The book takes in modern topics, such as graphene, carbon nanotubes and isotopic frequencies of molecules, as well as more traditional subjects: the vibrational and electronic states of molecules and solids, crystal field and ligand field theory, transition metal complexes, space groups, time reversal symmetry, and magnetic groups. With over 100 end-of-chapter exercises, this book is invaluable for graduate students and researchers in physics, chemistry, electrical engineering and materials science.

Table of contents

• Cover
• Applications of Group Theory to Atoms, Molecules, and Solids
• Title Page
• Copyright Page
• Contents
• Preface
• 1 Introductory example: Squarene
• 2 Molecular vibrations of isotopically substituted AB[sub(2)] molecules
• 3 Spherical symmetry and the full rotation group
• 4 Crystal-field theory
• 5 Electron spin and angular momentum
• 6 Molecular electronic structure: The LCAO model
• 7 Electronic states of diatomic molecules
• 8 Transition-metal complexes
• 9 Space groups and crystalline solids
• 10 Application of space-group theory: Energy bands for the perovskite structure
• 11 Applications of space-group theory: Lattice vibrations
• 12 Time reversal and magnetic groups
• 13 Graphene
• 14 Carbon nanotubes
• Appendix A Vectors and matrices
• Appendix B Basics of point-group theory
• Appendix C Character tables for point groups
• Appendix D Tensors, vectors, and equivalent electrons
• Appendix E The octahedral group, O and O[sub(h)]
• Appendix F The tetrahedral group, T[sub(d)]
• Appendix G Identifying point groups
• Index