Micro-Mesoporous Metallosilicates

Synthesis, Characterization, and Catalytic Applications

Peng Wu, Hao Xu

• Publisher: Wiley-VCH
• Year: 2024
• Print ISBN: 9783527350940
• eBook ISBN: 9783527839377
• Edition: 1
• Topic: Technology & Engineering
• Subtopic: Industrial & Technical Chemistry
• Index: Technology & Engineering

Micro-Mesoporous Metallosilicates

Up-to-date and in-depth text bridging the technology gap between fundamental research and industry-scale applications of porous materials for catalysis

Micro-Mesoporous Metallosilicates: Synthesis, Characterization, and Catalytic Applications comprehensively introduces the chemistry and catalytic technologies of metallosilicates, an important family of microporous crystalline zeolite and heteroatom-containing mesoporous materials, with a primary focus on design synthesis, characterization, theoretical studies, and catalytic applications of titanosilicates, tin-silicates, germanosilicates and Ti-mesosilica, and more.

The text covers recent advances in the synthesis of titanosilicates, including hydrothermal synthesis, dry-gel conversion, fluoride-assisted synthesis, and post-synthesis methods, along with the synthesis of metallosilicates with two-dimensional lamellar structures and their structural modifications as well as applications in selective oxidation reactions.

The text also discusses synthesis of germanosilicates with specially designed organic structure-directing agents, synthesis and catalytic applications of heteroatom-containing mesoporous silica, and dendritic mesoporous silica nanoparticles with unique wrinkled center-radial structures.

Overall, every important porous metallosilicate and its synthesis, characterization, pore engineering, catalytic application, and industrial technique and process are covered.

Specific sample topics discussed in Micro-Mesoporous Metallosilicates include:

• Chemical post-modifications of titanosilicates, in terms of the effects on transfer, adsorption/desorption, and surface reactions
• X-Ray based techniques, ultraviolet-visible-near infrared spectroscopy, Raman spectroscopy, and solid-state NMR spectroscopy
• Theoretical calculation as an effective tool and supplement to understand the catalytic active center, structural character, and Brønsted/Lewis acidity
• Titanosilicates in the liquid-phase epoxidation reaction of propylene and propylene chloride to corresponding epoxides
• Effects of particle sizes, oxidation state, and location sites of Au nanoparticles, and epoxidation performance of Ti-containing materials

Delivering cutting-edge research and bridging the technology gap between fundamental research and industrial applications, Micro-Mesoporous Metallosilicates is a valuable resource for chemists, materials scientists, chemical engineers, and experienced researchers in related fields.

Table of contents

• Cover
• Table of Contents
• Title Page
• Copyright
• Preface
• 1 Synthesis of Titanosilicates
• 2 Layered Heteroatom-Containing Zeolites
• 3 Synthesis and Catalytic Applications of Sn- and Zr-Zeolites
• 4 Synthesis of Germanosilicates
• 5 Structural Modifications on Germanosilicates
• 6 Heteroatom-Containing Dendritic Mesoporous Silica Nanoparticles
• 7 Chemical Post-Modifications of Titanosilicates
• 8 Spectroscopic Characterization of Heteroatom-Containing Zeolites
• 9 Theoretical Calculations of Heteroatom Substituted Zeolites
• 10 Catalytic Ammoximation of Ketones or Aldehydes Using Titanosilicates
• 11 Titanosilicate-Based Alkene Epoxidation Catalysis
• 12 Propylene Epoxidation with Cumene Hydroperoxide/Titanosilicates
• 13 Hydroxylation of Benzene and Phenol on Zeolite Catalysts
• 14 Bifunctional Titanosilicate Systems for the Gas-Phase Catalytic Propylene Epoxidation with Hydrogen and Oxygen
• 15 Zeolites Containing Heteroatoms/Metal Nanoparticles for Catalytic Conversion of Light Alkanes
• 16 Design and Applications of Single-Site Photocatalysis Using Metallosilicates
• Index
• End User License Agreement