The Chemistry of Ynamides
Development, Syntheses, and Applications in Organic Synthesis
- 720 pages
- English
- ePUB (mobile friendly)
- Available on iOS & Android
The Chemistry of Ynamides
Development, Syntheses, and Applications in Organic Synthesis
About this book
Ynamides contain a triple bond directly connected to a nitrogen atom that bears an electron-withdrawing group. They represent an especially useful and emerging class of reagents, notably because of their strongly polarized triple bond, which enables the development of unique chemical transformations. While they were discovered by Viehe in 1972, their chemistry has remained little investigated and the renaissance of ynamide chemistry started at the dawn of the 20th century with the development of efficient methods for their synthesis. Since then, ynamide chemistry has developed at a remarkably high rate, notably in the past 20 years. Although there are several reviews on ynamide chemistry, most of them are out of date or only focus on special aspects of ynamide chemistry and there is no book about ynamide chemistry yet. Thus, a comprehensive book on ynamide chemistry would be timely and is highly needed.
This book covers all aspects of ynamide chemistry, including their discovery, their syntheses, their application in heterocyclic chemistry, natural product synthesis, and organometallic chemistry, and their use as coupling reagents. It provides a systematic and comprehensive overview on ynamide chemistry for the researchers in this field, general readers interested in synthesis, and those who want to enter this field and need a comprehensive and up-to-date overview. Undoubtedly, this book will play a key role in connecting the past with the future to further foster the development of ynamide chemistry.
Frequently asked questions
- Essential is ideal for learners and professionals who enjoy exploring a wide range of subjects. Access the Essential Library with 800,000+ trusted titles and best-sellers across business, personal growth, and the humanities. Includes unlimited reading time and Standard Read Aloud voice.
- Complete: Perfect for advanced learners and researchers needing full, unrestricted access. Unlock 1.4M+ books across hundreds of subjects, including academic and specialized titles. The Complete Plan also includes advanced features like Premium Read Aloud and Research Assistant.
Please note we cannot support devices running on iOS 13 and Android 7 or earlier. Learn more about using the app.
Information
Table of contents
- Cover Page
- Half Title Page
- Title Page
- Copyright Page
- Contents
- Preface
- Chapter 1 The Discovery of Ynamines and Ynamides: A Historical Perspective
- Chapter 2 Synthesis of Ynamides
- Chapter 3 The Cationic Chemistry of Ynamides, Useful Precursors of Keteniminium Ions
- Chapter 4 The Anionic Chemistry and Carbometallation of Ynamides
- Chapter 5 Radical Reactions of Ynamides
- Chapter 6 Transition Metal-Catalyzed Reactions of Ynamides
- Chapter 7 Ynamides as Precursors of Carbenes and Carbenoids
- Chapter 8 Reversal of Regioselectivity in the Chemistry of Ynamides
- Chapter 9 Pericyclic Reactions of Ynamides
- Chapter 10 Ynamides in Multicomponent Reactions
- Chapter 11 Ynamides as Racemization-Free Coupling Reagents for Amide and Ester Bond Formation
- Chapter 12 Ynamides in the Synthesis of Natural/Biologically Relevant Products
- Index