Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis

Junliang Zhang, Wenbo Li

• Publisher: Elsevier
• Year: 2023
• Print ISBN: 9780323852258
• eBook ISBN: 9780323852265
• Topic: Scienze fisiche
• Subtopic: Chimica organica

Chiral Phosphorous Based Ligands in Earth-Abundant Transition Metal Catalysis summarizes the most significant progress in the field of chiral phosphine ligand chemistry and a broad range of earth-abundant transition metal/chiral phosphine ligand-catalyzed enantioselective transformations. The book provides an authoritative and in-depth understanding of important topics about asymmetric catalysis based on earth-abundant transition metals/chiral phosphine ligands, making it ideal for organic chemistry researchers working in the field of asymmetric catalysis, synthetic methodologies and total synthesis.The development of new chiral phosphine ligands to achieve precise stereo control in many earth-abundant transition metal-catalyzed reactions is a very important field in organic synthesis, materials science and medicinal chemistry. The asymmetric synthesis promoted by transition metal/chiral phosphine ligands provides one of the most ideal ways to produce valuable optically active chemicals. - Includes a discussion of state-of-the-art asymmetric organic reactions mediated by earth-abundant transition metals and chiral phosphine ligands - Features the progress and the prospect of chiral phosphine ligands in asymmetric transition metal catalysis - Covers the asymmetric reactivity modes of earth-abundant transition metals and phosphine ligands

Table of contents

• Title of Book
• Cover image
• Title page
• Table of Contents
• Copyright
• Contributors
• Acknowledgment
• Introduction
• Chapter 1 Design and synthesis of typical chiral bisphosphorus ligands
• Chapter 2 The progress of chiral phosphine ligands in asymmetric iron catalysis
• Chapter 3 Asymmetric transformations under cobalt catalysis
• Chapter 4 Asymmetric transformations under nickel catalysis
• Chapter 5 Copper/chiral phosphine ligand–catalyzed enantioselective 1,3-dipole cycloaddition reactions
• Chapter 6 Copper/phosphine-catalyzed asymmetric radical reactions
• Chapter 7 Asymmetric borylative functionalization of π systems by copper/chiral phosphine
• Chapter 8 Asymmetric hydrosilylation reactions by copper/chiral phosphine
• Chapter 9 Asymmetric transformations under copper hydride (CuH) catalysis
• Index