Mono-Olefins

Chemistry and Technology

F. Asinger

• Publisher: Pergamon
• Year: 2013
• Print ISBN:
  9780080115474
• eBook ISBN:
  9781483160962
• Topic: Technology & Engineering
• Subtopic: Chemistry
• Index: Chemistry

Mono-Olefins: Chemistry and Technology is a translation from the German and deals with the study of olefins from low ethylene to hexenes and olefins from the high hexenes to eicosenes. The book describes the gaseous or low-boiling olefins and the higher, normally liquid olefins (which have only a minor role in applications in the chemical industry). The olefins are considered important as they are added in the distillation of off-gases in refineries. Although the liquid olefins are used sparingly, these are needed to manufacture lubricants, synthetic detergents, and the higher aliphatic alcohols. The book then explains the three processes used to separate olefin containing mixtures of gases into fractions by the C-number or to convert olefins in the pure state: distillation, absorption, and adsorption. The author then describes the processes in manufacturing carburetor fuel from petroleum and natural gases. Petroleum oil is a mixture of paraffinic, naphthenic, and aromatic hydrocarbons and has no olefins. The text describes the complete process of refining petroleum into different products such as gasoline, kerosene, lubricants, and spotting benzenes. Then the book explains the polymerization of olefins to produce carburetor fuels either by the thermal method or catalytic method. The text notes some research made into double-bond isomerization in mono-olefins and their possible applications. This book is beneficial to industrial chemists, researchers, technical designers, and engineers whose works are related with oil refinery and fossil fuels.

Table of contents

• Front Cover
• Mono-Olefins: Chemistry and Technology
• Copyright Page
• Table of Contents
• PREFACE TO THE ENGLISH EDITION
• CHAPTER 1. Mono-olefins Necessarily Arising in Various Processes
• CHAPTER 2. The Direct Preparation of the Olefins
• CHAPTER 3. The Concentration or Isolation of Olefins from Olefin-Containing Gases
• CHAPTER 4. The Manufacture of High-Efficiency Carburettor Fuels
• CHAPTER 5. The Working Up of Lower, Normally Gaseous, Paraffins and Mono-Olefins to give Carburettor Fuels
• CHAPTER 6. The Chlorination of the Olefins
• CHAPTER 7. The Hydration of Olefins to Alcohols
• CHAPTER 8. Various Addition Reactions of the Olefins
• CHAPTER 9. The Hydroformylation of the Olefins (ROELEN reaction; Oxo reaction)
• CHAPTER 10. The Polymerization of the Mono-olefins to give Plastics and Lubricants
• CHAPTER 11. The Alkylation of Aromatic Compounds with Olefins
• CHAPTER 12. Double-bond Isomerization in the Mono-olefins and its Practical Importance
• Index