Ions and Ion Pairs and Their Role in Chemical Reactions
eBook - PDF

Ions and Ion Pairs and Their Role in Chemical Reactions

Invited Lectures Presented at the Symposium on Ions and Ion Pairs and Their Role in Chemical Reactions, Syracuse, NY, USA, 30 May - 2 June 1978

  1. 145 pages
  2. English
  3. PDF
  4. Available on iOS & Android
eBook - PDF

Ions and Ion Pairs and Their Role in Chemical Reactions

Invited Lectures Presented at the Symposium on Ions and Ion Pairs and Their Role in Chemical Reactions, Syracuse, NY, USA, 30 May - 2 June 1978

About this book

Ions and Ion Pairs and their Role in Chemical Reactions covers a wide spectrum of ion pairing phenomena. This book focuses on the structure, dynamics, and energetics of ions and ion pairs and their complexes with solvent molecules and ion coordinating ligands in the solid, liquid, and gaseous state. Organized into 12 chapters, this book begins with an overview of the theory and complications involved in dipole moment measurements in slightly conductive polar solvents. This text then explores the measurement of gas phase ion-molecule equilibria by special spectrometric methods. Other chapters consider the NMR experiments on potassium biphenyl, sodium biphenyl, and rubidium biphenyl, dissolved in different solvents. This book discusses as well the ion pair formation of some cyclic conjugated carbanions and nitranions. The final chapter deals with the information obtained from relaxation measurements on processes such as ionic dissociation, aggregation, and solvent separation. This book is a valuable resource for chemists, organic chemists, and quantum chemists.

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Information

Publisher
Pergamon
Year
2013
Print ISBN
9780080223551
eBook ISBN
9781483284576
Topic
Physical Sciences
Subtopic
Chemistry
Index
Chemistry

Table of contents

  1. Front Cover
  2. Ions and Ion Pairs and their Role in Chemical Reactions
  3. Copyright Page
  4. Table of Contents
  5. Dedication
  6. PREFACE
  7. CHAPTER 1. STRUCTURE OF SOLVATED ION PAIRS FROM ELECTRIC DIPOLE MOMENTS
  8. CHAPTER 2. INFORMATION ON ION-SOLVENT INTERACTIONS OBTAINED FROM THE STUDY OF ISOLATED COMPLEXES CONTAINING THE ION AND A SMALL NUMBER OF SOLVENT MOLECULES
  9. CHAPTER 3. STRUCTURE OF ALKALI BIPHENYL ION PAIRS IN SOLUTION AND IN THE SOLID STATE
  10. CHAPTER 4. OPTICAL AND NMR INVESTIGATIONS ON ALKALI ION PAIRS OF CARBANIONS AND NITRANIONS
  11. CHAPTER 5. MULTINUCLEAR NMR STUDIES OF ALKALI IONS IN NONAQUEOUS SOLVENTS
  12. CHAPTER 6. MACROCYCLIC LIGANDS ON POLYMERS
  13. CHAPTER 7. FAST REACTION STUDIES OF CARBOCATIONS IN SOLUTION
  14. CHAPTER 8. ION PAIRING AND REACTIVITY OF β-KETOENOLATES
  15. CHAPTER 9. STEREOCHEMICAL EFFECTS OF ION PAIRING IN ANIONIC VINYL OLIGOMERIZA-TION AND RELATED CARBANION REACTIONS
  16. CHAPTER 10. THE REACTION OF CATIONS WITH ANIONS IN SOLUTION
  17. CHAPTER 11. FORMATION AND REACTIVITIES OF FREE IONS IN CATIONIC POLYMERISATION
  18. CHAPTER 12. THE DYNAMICS OF ELECTRIC FIELD EFFECTS IN ION PAIRING PROCESSES

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