Cyanoximes

Chemistry, Coordination and Organometallic Compounds and their Applications

Nikolay Gerasimchuk

• Publisher: Elsevier
• Year: 2025
• eBook ISBN:
  9780443288524
• Topic: Physical Sciences
• Subtopic: Inorganic Chemistry

Cyanoximes: Chemistry, Coordination and Organometallic Compounds and their Applications contains vast information about the use of cyanoximes as small molecules ligands in coordination, bioinorganic, and in organometallic chemistry. In addition, it presents the structural chemistry of these compounds and shows their most interesting spectroscopic properties, along with the practical aspects of their chemistry. Methods of syntheses, stereochemistry of cyanoximes ligands, their structures and properties, as well as the most interesting coordination compounds are described, as well as a broad spectrum of practical applications of both cyanoximes and their metal complexes.These simple, low molecular weight organic molecules represent a series of new excellent ampolydentate ligands for coordination chemistry. Currently, 48 cyanoximes are known, and users will find more than two hundreds cyanoxime complexes synthesized and studied using a variety of different spectroscopic methods and X-ray analysis. - Presents a systematic approach to the presentation, description, and properties of cyanoxines, a new class of compounds - Covers detailed descriptions of the most interesting and unique chemical and structural features of this new class of organic compounds and their metal complexes - Analyzes areas of potential application of all investigated compounds

Table of contents

• Title of Book
• Chapter 1.1 Introduction
• Chapter 1.2 Oximes are intermediate compounds
• Chapter 1.3 Currently known and studied cyanoximes
• Chapter 1.4 Stereochemistry of cyanoximes
• Chapter 1.5 Deprotonation of cyanoximes and formation of colored anions
• Chapter 1.6 UV-visible spectra of anionic cyanoximes: solvatochromism and planochromism
• Chapter 1.7 Solid state structures of ionic salts of cyanoximes
• Chapter 1.8 Formation of unique acid-salts of cyanoximes
• Chapter 1.9 Ligands with two and three cyanoxime moieties
• Chapter 1.10 Cyanoxime anions are unique ampolidentate ligands for coordination and organometallic chemistry!
• Chapter 2.1 Rationale and motivation for the synthesis of metal-containing cyanoximates
• Chapter 2.2 Preparation of Werner-type coordination compounds involving oximes
• Chapter 2.3 Cyanoximates of main group metals
• Chapter 2.4 Transition metals cyanoximates
• Chapter 3.1 Purpose of synthesis and characterization of series of organometallic compounds
• Chapter 3.2 Organotin(IV) cyanoximates
• Chapter 3.3 Organoantimony(V) cyanoximates
• Chapter 3.4 Organotellurium(IV) compounds
• Chapter 3.5 Organometallic cyanoximates of transition metals
• Chapter 4.1 Biomedical field
• Chapter 4.2 Technological areas
• Appendix A
• Appendix B
• Appendix C
• Appendix D
• Appendix E
• Appendix F
• Appendix G
• Appendix H
• Appendix I
• Appendix J
• Appendix K
• Appendix L
• Appendix M
• Appendix N
• Afterword
• Index