The Three Pillars of Confidence in Chemical Measurement
eBook - ePub

The Three Pillars of Confidence in Chemical Measurement

A Collection of Essays

  1. 98 pages
  2. English
  3. ePUB (mobile friendly)
  4. Available on iOS & Android
eBook - ePub

The Three Pillars of Confidence in Chemical Measurement

A Collection of Essays

About this book

What if everything you thought you knew about uncertainty in chemical measurement was incomplete – or even misleading?

For more than sixty years, Michael Thompson has lived at the coalface of chemical measurement: analysing thousands of samples; developing and validating methods; teaching generations of analysts; studying huge amounts of other people's data; and exploring quality frameworks that define the field. Along the way, his conviction grew steadily stronger that qualimetrics – the science of measurement quality – needs a thorough rethink.

In this sharp, provocative and often witty collection of essays, the author explores the fault lines embedded in today's 'official' metrological landscape. Why are some pillars of chemical measurement taken as gospel when they fail under scrutiny? How did essential concepts become so obscured by dogma and terminology? Drawing on a lifetime of experience, the author sheds new light on topics including:

  • traceability and mass fractions;
  • collaborative trials, proficiency testing and method validation – their flaws and strengths;
  • sampling uncertainties, too often ignored yet as important as measurement itself; and
  • how a more scientific, less dogmatic mindset could move the field forward.

Interwoven with personal recollections – from mentors and memorable characters to the daily realities of analytical work – these essays offer both depth and humanity. Whether you are a practising analyst, a metrologist, a student or simply someone curious about how we know what we know in chemistry, this book challenges assumptions and argues passionately for a more coherent future for qualimetrics.

Table of contents

  1. Cover
  2. Title
  3. Copyright
  4. Preface
  5. Acknowledgements
  6. Contents
  7. 1 Introduction
  8. 2 The Three Pillars of Confidence
  9. 3 Robust Statistics
  10. 4 Rounding in Chemical Measurement and Reporting
  11. 5 In Praise of Mass Fractions
  12. 6 Duplicate Measurements Are Valuable
  13. 7 p-Values in Significance Testing
  14. 8 Improving Collaborative Trials
  15. 9 Off Limits
  16. 10 Samples and Their Uncertainties
  17. 11 The ‘Jaws Syndrome’ and Analytical Chemists
  18. 12 Experiments in Qualimetrics
  19. 13 Blowing the Horwitz Trumpet
  20. 14 Theobald and the Pipette
  21. 15 Validation in Chemical Measurement: A Critique
  22. 16 “All Results Are Wrong”
  23. 17 Certification of Chemical Matrix Reference Materials as Consensus Values Derived from Proficiency Tests
  24. 18 ‘Empirical’ and ‘Rational’ Analytical Procedures
  25. 19 Stiffening-up Proficiency Testing (and Its Accreditation)
  26. 20 Bosses
  27. 21 Misconceptions in the ‘Metrological Paradigm’ of Chemical Measurement

Trusted by 375,005 students

Access to over 1.5 million titles for a fair monthly price.

Study more efficiently using our study tools.

Information

Edition
1
Year
2026
Print ISBN
9781837074549
eBook ISBN
9781837074563

Frequently asked questions

Yes, you can cancel anytime from the Subscription tab in your account settings on the Perlego website. Your subscription will stay active until the end of your current billing period. Learn how to cancel your subscription
No, books cannot be downloaded as external files, such as PDFs, for use outside of Perlego. However, you can download books within the Perlego app for offline reading on mobile or tablet. Learn how to download books offline
Perlego offers two plans: Essential and Complete
  • Essential is ideal for learners and professionals who enjoy exploring a wide range of subjects. Access the Essential Library with 800,000+ trusted titles and best-sellers across business, personal growth, and the humanities. Includes unlimited reading time and Standard Read Aloud voice.
  • Complete: Perfect for advanced learners and researchers needing full, unrestricted access. Unlock 1.5M+ books across hundreds of subjects, including academic and specialized titles. The Complete Plan also includes advanced features like Premium Read Aloud and Research Assistant.
Both plans are available with monthly, semester, or annual billing cycles.
We are an online textbook subscription service, where you can get access to an entire online library for less than the price of a single book per month. With over 1.5 million books across 990+ topics, we’ve got you covered! Learn about our mission
Look out for the read-aloud symbol on your next book to see if you can listen to it. The read-aloud tool reads text aloud for you, highlighting the text as it is being read. You can pause it, speed it up and slow it down. Learn more about Read Aloud
Yes! You can use the Perlego app on both iOS and Android devices to read anytime, anywhere — even offline. Perfect for commutes or when you’re on the go.
Please note we cannot support devices running on iOS 13 and Android 7 or earlier. Learn more about using the app
Yes, you can access The Three Pillars of Confidence in Chemical Measurement by Michael Thompson in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Literary Essays. We have over 1.5 million books available in our catalogue for you to explore.