Organic Reaction Mechanisms 2012
eBook - ePub

Organic Reaction Mechanisms 2012

An annual survey covering the literature dated January to December 2012

  1. English
  2. ePUB (mobile friendly)
  3. Available on iOS & Android
eBook - ePub

Organic Reaction Mechanisms 2012

An annual survey covering the literature dated January to December 2012

About this book

Organic Reaction Mechanisms 2012, the 48th annual volume in this highly successful and unique series, surveys research on organic reaction mechanisms described in the available literature dated 2012. The following classes of organic reaction mechanisms are comprehensively reviewed:

  • Reaction of Aldehydes and Ketones and their Derivatives
  • Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
  • Oxidation and Reduction
  • Carbenes and Nitrenes
  • Nucleophilic Aromatic Substitution
  • Electrophilic Aromatic Substitution
  • Carbocations
  • Nucleophilic Aliphatic Substitution
  • Carbanions and Electrophilic Aliphatic Substitution
  • Elimination Reactions
  • Polar Addition Reactions
  • Cycloaddition Reactions
  • Molecular Rearrangements

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Information

Publisher
Wiley
Year
2015
Print ISBN
9781118362594
eBook ISBN
9781118930762
Edition
1
Topic
Physical Sciences
Subtopic
Organic Chemistry

Chapter 1
Reactions of Aldehydes and Ketones and their Derivatives

A.C. Knipe
Faculty of Life and Health Sciences, University of Ulster, Coleraine, Northern Ireland
  1. Formation and Reactions of Acetals and Related Species
  2. Reactions of Glucosides and Nucleosides
  3. Reactions of Ketenes and Ketenimines
  4. Formation and Reactions of Nitrogen Derivatives
    1. Imines: Synthesis, Tautomerism, and Catalysis
    2. The Mannich and Nitro-Mannich reactions
    3. Addition of organometallics
    4. Other alkenylations, allylations, and arylations of imines
    5. Oxidation and reduction of imines
    6. Iminium species
    7. Imine cycloadditions
    8. Other reactions of imines
    9. Oximes, Hydrazones, and Related Species
  5. C–C Bond Formation and Fission: Aldol and Related Reactions
    1. Reviews of Organocatalysts
    2. Asymmetric Aldols Catalysed by Proline, Its Derivatives, and Related Catalysts
    3. Other Asymmetric and Diastereoselective Aldols
    4. Mukaiyama and Vinylogous Aldols
    5. Other Aldol and Aldol-type Reactions
    6. The Henry (Nitroaldol) Reaction
    7. The Baylis–Hillman Reaction and Its Morita Variant
    8. Allylation and related reactions
    9. Alkynylations
    10. Michael Additions
    11. Miscellaneous Condensations
  6. Other Addition Reactions
    1. Addition of Organozincs
    2. Arylations
    3. Addition of Other Organometallics, Including Grignards
    4. The Wittig Reaction
    5. Hydrocyanation, Cyanosilylation, and Related Additions
    6. Hydrosilylation, hydrophosphonylation, and related reactions
    7. Miscellaneous additions
  7. Enolization and Related Reactions
    1. Enolization
    2. α-Alkylation, α-Halogenation, and Other α-Substitutions
  8. Oxidation and Reduction of Carbonyl Compounds
    1. Regio-, Enantio-, and Diastereo-selective Reduction Reactions
    2. Other Reduction Reactions
    3. Oxidation Reactions
  9. Cycloadditions
  10. Other Reactions
  11. References

Formation and Reactions of Acetals and Related Species

Mechanisms and energetics for BrĂžnsted-acid-catalysed glucose condensations, dehydration, and isomerization reactions have been reviewed.1 Recent developments in the asymmetric synthesis of spiroketals have been reviewed and the potential for further application of transition metal catalysis and organocatalysis has been highlighted.2
c1h001
Hemiacetal formation from formaldehyde and methanol has been studied by intrinsic reactivity analysis at the B3LYP/6-311++G(d,p) level and the beneficial combined assistance of watermolecules and BrĂžnsted acids has been quantified.3 Theoretical study of hemiacetal formation from methanol with derivatives of CH3CHO (X = H, F, Cl, Br, and I) has shown that the energy barrier can be reduced by a catalytic molecule (MeOH or hemiacetal product).4
A combined experimental and density functional theory (DFT) study of the thermal decomposition o...

Table of contents

  1. Cover
  2. Title Page
  3. Copyright
  4. Table of Contents
  5. Contributors
  6. Preface
  7. Chapter 1: Reactions of Aldehydes and Ketones and their Derivatives
  8. Chapter 2: Reactions of Carboxylic, Phosphoric, and Sulfonic Acids and their Derivatives
  9. Chapter 3: Oxidation and Reduction
  10. Chapter 4: Carbenes and Nitrenes
  11. Chapter 5: Aromatic Substitution
  12. Chapter 6: Carbocations
  13. Chapter 7: Nucleophilic Aliphatic Substitution
  14. Chapter 8: Carbanions and Electrophilic Aliphatic Substitution
  15. Chapter 9: Elimination Reactions
  16. Chapter 10: Addition Reactions: Polar Addition
  17. Chapter 11: Addition Reactions: Cycloaddition
  18. Chapter 12: Molecular Rearrangements
  19. Author Index
  20. Subject Index
  21. End User License Agreement

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Yes, you can access Organic Reaction Mechanisms 2012 by A. C. Knipe in PDF and/or ePUB format, as well as other popular books in Physical Sciences & Organic Chemistry. We have over 1.5 million books available in our catalogue for you to explore.