
Asymmetric Synthesis II
More Methods and Applications
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Asymmetric Synthesis II
More Methods and Applications
About this book
After the overwhelming success of Asymmetric Synthesis - The Essentials, displaying a broad range of organic asymmetric syntheses, this is the second edition with latest subjects and authors. While the aim of the first edition was mainly to honor the achievements of the pioneers in asymmetric syntheses, the aim of this new edition was bringing the current developments, especially from younger colleagues, to the attention of students. The format of the book remained unchanged, i.e. short conceptual overviews by young leaders in their field including a short biography of the authors. The growing multidisciplinary research within chemistry is reflected in the selection of topics including metal catalysis, organocatalysis, physical organic chemistry, analytical chemistry, and its applications in total synthesis, materials research and industry.
The prospective reader of this book is a graduate or undergraduate student of advanced organic chemistry as well as the industrial chemist who wants to get a brief update on the current developments in the field.
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Information
Table of contents
- Cover
- Related Titles
- Title Page
- Copyright
- List of Contributors
- Chapter 1: Catalytic Enantioselective Alkylation of Prochiral Ketone Enolates
- Chapter 2: Point-to-Planar Chirality Transfer in Total Synthesis: Scalable and Programmable Synthesis of Haouamine A and Its Atropisomer
- Chapter 3: Tethered Aminohydroxylation
- Chapter 4: Organocatalyzed Transformations of α, β-Unsaturated Carbonyl Compounds through Iminium Ion Intermediates
- Chapter 5: The Renaissance of Silicon-Stereogenic Silanes: A Personal Account
- Chapter 6: Asymmetric Dienamine Activation
- Chapter 7: Asymmetric Brønsted Acid Catalysis
- Chapter 8: Quaternary Stereogenic Centers by Enantioselective β-Carbon Eliminations from tert-Cyclobutanols
- Chapter 9: Total Synthesis of Oseltamivir and ABT-341 Using One-Pot Technology
- Chapter 10: Enantioselective Annulations with Chiral N-Mesityl N-Heterocyclic Carbenes
- Chapter 11: Asymmetric Counteranion-Directed Catalysis (ACDC)
- Chapter 12: Enantioselective Organo-SOMO Catalysis: a Novel Activation Mode for Asymmetric Synthesis
- Chapter 13: Enantioselective Passerini Reaction
- Chapter 14: Rapid Enantiomeric Excess Determination
- Chapter 15: Asymmetric Catalysis of Reversible Reactions
- Chapter 16: Exploiting Fluorine Conformational Effects in Organocatalyst Design: The Fluorine–Iminium Ion Gauche Effect
- Chapter 17: Dutch Resolution
- Chapter 18: Construction of anti-Me-OH Vicinal Relationships in Polyketides
- Chapter 19: Photoswitchable General Base Catalysts
- Chapter 20: Asymmetric Halonium Addition to Olefins
- Chapter 21: Catalytic Asymmetric Gosteli–Claisen Rearrangement (CAGC)
- Chapter 22: Biomimetic Total Synthesis of the Penifulvin Family
- Chapter 23: Catalyst-Controlled 1,3-Polyol Syntheses
- Chapter 24: Enantioselective Carbonyl Allylation and Crotylation from the Alcohol Oxidation Level via C–C Bond Forming Transfer Hydrogenation
- Chapter 25: Stereoselective Synthesis with Hypervalent Iodine Reagents
- Chapter 26: Asymmetric Gold-Catalyzed Reactions
- Chapter 27: Asymmetric Catalysis in the Total Synthesis of Lipids and Polyketides
- Chapter 28: The Evolving Role of Biocatalysis in Asymmetric Synthesis
- Chapter 29: Bifunctional Thiourea Catalysts
- Chapter 30: Catalytic Asymmetric (4 + 3) Cycloadditions Using Allenamides
- Chapter 31: Application of the Achmatowicz Rearrangement for the Synthesis of Oligosaccharides
- Chapter 32: Asymmetric C–C Bond Formation Using Chiral Phosphoric Acid
- Chapter 33: Asymmetric C–H Bond Functionalization
- Chapter 34: Asymmetric C–C Bond Formation Using Chiral Guanidine Catalysts
- Chapter 35: Enantioselective Synthesis of Lactones via Rh-Catalyzed Ketone Hydroacylation
- Chapter 36: Radical Haloalkylation
- Chapter 37: Asymmetric Hydrovinylation of Alkenes
- Chapter 38: Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions
- Chapter 39: N-Heterocyclic Carbene-Catalyzed Aldol Desymmetrizations
- Chapter 40: Strategies for the Asymmetric Total Synthesis of Natural Products: “Chiral Pool” versus Chiral Catalysts
- Chapter 41: Dynamic Kinetic Asymmetric Transformations Involving Carbon–Carbon Bond Cleavage
- Chapter 42: Iron-Catalyzed Allylic Substitutions
- Chapter 43: Asymmetric Conia-Ene Carbocyclizations
- Chapter 44: Tactics and Strategies in the Total Synthesis of Chlorosulfolipids
- Chapter 45: Linear Free Energy Relationships (LFERs) in Asymmetric Catalysis
- Chapter 46: Asymmetric Diamination of Alkenes
- Chapter 47: Enzymatic Asymmetric Synthesis of Tertiary Alcohols
- Chapter 48: Oxidative Dearomatization and Organocatalytic Desymmetrization
- Chapter 49: Total Synthesis of All (–)-Agelastatin Alkaloids
- Index