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Heterocyclic Chemistry, 3rd Edition
John A. Joule
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eBook - ePub
Heterocyclic Chemistry, 3rd Edition
John A. Joule
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Covering the fundamentals of heterocyclic reactivity and synthesis, this book teaches the subject in a way that is understandable to graduate students. Recognizing the level at which heterocyclic chemistry is often taught, the authors have included advanced material that make it appropriate for postgraduate courses. The text discusses the chemical reactivity and synthesis of particular heterocyclic systems. Exercises and solutions help students understand and apply the principles. Original references are included throughout, as well as many review references.
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Informations
Structures and main physical properties of aromatic heterocycles | 1 |
This chapter describes the structures of aromatic heterocycles and gives a brief summary of some physical properties.1 The treatment we use is the valence-bond description, which we believe is sufficient for the understanding of all heterocyclic reactivity, perhaps save some very subtle effects, and is certainly sufficient for a general text-book on the subject. The more fundamental molecular-orbital description of aromatic systems is still not so relevant to the day-to-day interpretation of heterocyclic reactivity, though it is necessary in some cases to utilise frontier orbital considerations,2 however such situations do not fall within the scope of this book.
1.1 CARBOCYCLIC AROMATIC SYSTEMS
1.1.1 Structures of benzene and naphthalene
The concept of aromaticity as represented by benzene is a familiar and relatively simple one. The difference between benzene on the one hand and alkenes on the other is well known: the latter react by addition with electrophiles, such as bromine, whereas benzene reacts only under much more forcing conditions and then nearly always by substitution. The difference is due to the cyclic arrangement of six Ï-electrons in benzene: this forms a conjugated molecular orbital system which is thermodynamically much more stable than a corresponding non-cyclically conjugated system. The additional stabilisation results in a diminished tendency to react by addition and a greater tendency to react by substitution for, in the latter manner, survival of the original cyclic conjugated system of electrons is ensured in the product. A general rule proposed by HĂŒckel in 1931 states that aromaticity is observed in cyclically conjugated systems of 4n + 2 electrons, that is with 2, 6, 10, 14, etc., Ï-electrons; by far the majority of monocyclic aromatic, and heteroaromatic, systems are those with 6 Ï-electrons.
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Normes de citation pour Heterocyclic Chemistry, 3rd Edition
APA 6 Citation
Joule, J. (2020). Heterocyclic Chemistry, 3rd Edition (3rd ed.). CRC Press. Retrieved from https://www.perlego.com/book/2011760/heterocyclic-chemistry-3rd-edition-pdf (Original work published 2020)
Chicago Citation
Joule, John. (2020) 2020. Heterocyclic Chemistry, 3rd Edition. 3rd ed. CRC Press. https://www.perlego.com/book/2011760/heterocyclic-chemistry-3rd-edition-pdf.
Harvard Citation
Joule, J. (2020) Heterocyclic Chemistry, 3rd Edition. 3rd edn. CRC Press. Available at: https://www.perlego.com/book/2011760/heterocyclic-chemistry-3rd-edition-pdf (Accessed: 15 October 2022).
MLA 7 Citation
Joule, John. Heterocyclic Chemistry, 3rd Edition. 3rd ed. CRC Press, 2020. Web. 15 Oct. 2022.