Interactions of Biochar and Herbicides in the Environment

Kassio Ferreira Mendes, Kassio Ferreira Mendes

• Éditeur: CRC Press
• Année: 2022
• ISBN:
  9781000592924
• Édition: 1
• Sujet: Ciencias biológicas
• Sous-sujet: Botánica

Interactions of Biochar and Herbicides in the Environment details how biochar interferes with herbicide behavior which includes processes such as sorption-desorption, runoff, leaching, and degradation in soil and weed control efficacy. The book provides essential information on biochar applications in agriculture, production systems, and the physicochemical properties of biochar and herbicides, and their interactions.

Features:

• Elucidates the physicochemical characteristics of biochar that affect herbicide bioavailability in soil solution

• Demonstrates the remediation of herbicide-contaminated waters with the addition of biochar to avoid environmental impacts to aquatic organisms

• Describes numerous agronomic and environmental benefits of biochar and its potential as a soil amendment to herbicide remediation

• Includes diagrams of herbicide behavior in the environment to further the user's knowledge

Written by a team of international experts, Interactions of Biochar and Herbicides in the Environment is a valuable resource for students and professionals involved with weed science and soil pollution, and is of great interest to those concerned with pesticides and their fate in the environment.

1 Agricultural Applications of Biochar

Mingxin Guo^1* and Weiping Song²

DOI: 10.1201/9781003202073-1

¹ Department of Agriculture and Natural Resources, Delaware State University, Dover, DE 19901, USA ²Department of Chemistry, Delaware State University, Dover, DE 19901, USA *Corresponding author: [email protected].

CONTENTS

1.1 Introduction

1.2 Quality Variations of Various Biochar Products

1.3 Potential Benefits of Biochar Amendment in Agricultural Applications

1.3.1 Soil Physical Health Amelioration by Biochar Amendment

1.3.2 Soil Chemical Health Amelioration by Biochar Amendment

1.3.3 Soil Biological Health Amelioration by Biochar Amendment

1.3.4 Crop Growth and Productivity Improvement by Biochar Amendment

1.4 Right Biochar Application Programs in Agricultural Production

1.4.1 Right Biochar Source

1.4.2 Right Biochar Application Rate

1.4.3 Right Biochar Placement to Soil

1.5 Status and Challenges of Agricultural Applications of Biochar

1.6 Summary and Concluding Remarks

Acknowledgments

References

1.1 INTRODUCTION

Biochar, a charcoal-like solid residual product from thermochemical processing of biomass materials, has been intensively explored in the past two decades as a soil amendment for promoting agricultural production. The idea of using biochar to enhance soil health and improve the crop productivity originated from the discovery of Terra Preta de Índio (meaning Amazonian Dark Earth in Portuguese) in the Amazon Basin in the late nineteenth century (Guo et al. 2016a). Subsequent research suggested that Terra Preta de Índio is a legacy of ancient Amazonian inhabitants who added charred wood, plant ash, manure, and fish bones to local land soil (Sombroke 1966; Woods and McCann 1999; Glaser et al. 2000). Even after 500–2000 years of natural weathering and leaching, Terra Preta de Índio soils demonstrate significantly higher organic carbon (OC) contents and remarkably greater crop yield relative to the adjacent control soils (Sombroke 1966; Lima et al. 2002), implicating the capability of biochar to persistently sustain soil fertility and health.

Biochar is commonly defined as “the fine-grained or granular charcoal made from heating vegetative biomass, bones, manure solids, or other plant-derived organic residues in an oxygen-free or oxygen-limited environment and used as a soil amendment for agricultural and environmental purposes” (Guo et al. 2016b). Theoretically, all solid biomass materials can be used to manufacture biochar. Researchers have tested a wide variety of bio-derived organic residues as biochar feedstocks, including hard wood, soft wood, saw dust, scrap wood and shavings, tree barks, tree leaves, pine needles, greenwaste, switchgrass, Miscanthus, fescue straw, corn stover, corn stalk, corn cobs, cotton stalk, wheat straw, rice straw, rice husk, soybean straw, rapeseed straw, pepper straw, peanut hull, peacan shell, palm shell, coconut shell, orange peel, olive pomace, sugarcane bagasse, cottonseed meal, poultry litter, cow manure, swine manure solids, sewage sludge, cattle carcass, bone meal, and solid organic municipal waste (Guo, Song et al. 2020). The feedstock materials were generally dried; processed into small pieces, grains, or pellets; and then converted to biochar through pyrolysis (heating at 300–700°C without air) or gasification (heating at 500–900°C with controlled air supply) (Guo, Xiao et al. 2020). During the thermochemical carbonization processes, 10–65% of the feedstock OC was recovered in biochar, phosphorus (P) was nearly preserved, while the loss of nitrogen (N) was tremendous (Song and Guo 2012; Guo, Song et al. 2020). Considering the accessibility, collection infrastructure, and economic viability, crop residues (e.g., corn stover, wheat straw, and rice husk) and forest debris (e.g., floor litter, tree trimmings, and wood waste) are promising feedstocks for field-scale production of agricultural-use biochar. Specialty food-processing wastes like nutshells, olive pomace, sugarcane bagasse, and cottonseed meal are limited in supply and, therefore, may serve a localized biochar feedstock or be simply added to the main feedstock stream. Organic refuses in municipal solid waste may contain toxic elements (e.g., heavy metals) that contaminate the resulting biochar products. Conversion to biochar is an effective method to sterilize and stabilize animal wastes such as carcass, bones, manures, and biosolids, yet the significant feedstock N losses incurred by high-temperature thermochemical treatment (e.g., at more than 400°C) are a major concern. Biochar is also a byproduct of wood pyrolysis to harvest bio-oil (a liquid biofuel) and wood gasification to produce syngas (a gaseous biofuel) (Guo, Xiao et al. 2020). Utilization of such biochar by-products in agricultural production is a value-added approach to promote the bioenergy indu...