Part 1
MAKING SEDIMENT
ā¦ the soil which has kept breaking away from the high lands during these ages and these disasters, forms no pile of sediment worth mentioning, as in other regions, but keeps sliding away ceaselessly and disappearing in the deep.
Plato, Critias, Vol. 9, Loeb Classical Library
Introduction
The noun sediment comes to the English language from the Latin root sedimentum, meaning settling or sinking down,aform ofthe verb sedere,to sit orsettle. In earth and environmental sciences, sediment has a wide context that includes many forms of organic and mineral matter. In Part 1 we look more deeply at the origins of the sediment that occurs on and under the surface of the solid planets and which may be used to infer past environmental conditions and changes. Sediment accumulations may be grandly viewed as the great stratal archive of past surface environments, or more basically asādirtā. There has been sediment on the surface of the Earth since the Archaean, with the oldest known sediment grains dating from at least 4.4Ga (Part 1 Fig. 1). Sediment also mantles the surface of many other planets and their satellites, notably Mars, Venus and Saturnās moon, Titan.
In scientific usage, Earthās sediment is best divided into three end-members:
- clasticāoriginating from pre-existing rock outside a depositional area as transported grains, the commonest being mineral silicate grains, known widely as siliciclastic sediment;
- chemicalābeing the result of inorganic or organically mediated chemical precipitation within the depositional area;
- biologicalāderived from skeletal material associated with living tissues.
These simple divisions are robust enough to include even the highly esoteric sediment forms that are turning up in the wider Solar System, like the solid ice particles transported and deposited by liquid methane on Titan.Ofcourse there are unusual, hybridormixed origins for some sediment but these can easily be accommodated (e.g. bioclastic, volcaniclastic). Note that the classification is restricted to grains that were sedimented; there are sedimentary horizons in the stratigraphic record that originated as precipitates below the deposited sediment surface, often bacteri-ally controlled. These were never sedimented as such and are considered as secondary or diagenetic sediments that post-dated physical deposition of host primary sediment. Deposited sediment accumulates as successive layers, termed strata, and such deposits as a whole are said to be stratified. The succession of strata in any given deposit is controlled by environmental factors and their correct interpretation involves a deep understanding of how present and past environments have evolved over time.
The chemical and biochemical processes that produce sediment also give other soluble byproducts; these chemical species control oceanic and atmospheric composition and provide long-term sourcing for base cations that nourish plant life and counteract acid deposition in temperate forested catchments. Chemical earth-surface processes have undoubtedly changed over deep geological time, in response to atmospheric and hydrological changes, whilst biological processes have changed hand-in-hand with organic evolution. By this view, sediment production is an accident of weathering and evolutionāa waste product. Ever since the Archaean, the planet has ālearntā how to cope with this waste, just like it has with the waste oxygen produced during plant photosynthesis. There was no predeterminism associated with the processes of sediment production on early Earth or any other planet. Sediment simply fell out (forgive the pun) of the rock cycle in which primary rock is chemically and physically altered. Compare for example sediment on the Moon with the Earth.In the former the sediment is a fragmented remnant from past meteoritic impact events. In the latter sediment is highly varied in its origins, composition, size and physical properties. Its role as an accidental part of the Rock Cycle establishes sedimentology as a fundamental part of Earth System Science. Indeed, as one nice semi-popular review entitled it a decade ago (Stanley & Hardie, 1999), from the point-of-view of calcareous sediment, āHypercalcification: Paleontology Links Plate Tectonics and Geochemistry to Sedimentologyā. We shall examine such grand claims later in this book (Chapter 23).
Chapter 1
CLASTIC SEDIMENT AS A CHEMICAL AND PHYSICAL BREAKDOWN PRODUCT
Few ken to whom this muckle monument stands, Some general or admiral Iāve nae doot, On the hill-top whaur weather lang syne Has blotted its inscribed palaver oot.
Hugh MacDiarmid, āThe Monumentā, 1936, Complete Poems, Vol. 1, Carcanet, 1993.
1.1 Introduction: clastic sedimentsāāaccidentsā of weathering
Terrestrial clastic sedimentary rocks are usually quite different in their composition from the igneous and metamorphic rocks that sourced them. This is because they are derived from an altered regolith with a soil profile produced by chemical weathering of pristine bedrock and the source of mineral grains for such sediment. For example, feldspar is the commonest mineral in bedrock of the Earthās continental crust (about 60% of the total) but quartz is usually predominant in clastic sediments and sedimentary rocks. Despite this difference the principle of conservation of mass tells us that for all elements present in the exposed crust and released by weathering, exactly the same levels of abundance must occur in the average total sedimentary mass. Thus the average chemical composition of all sediments is roughly that of the igneous rock, granodiorite, representing the mean composition of middle to upper continental crust.
It is traditional to divide rock weathering into physical and chemical components, but in reality the two are inextricably interlinked. Water is the chief reactant and plays a dual role since it also transports away both dissolved and solid weathering products. Earthispresentlyuniqueinits abundanceofwater and water vapour, yet Mars also had an earlier watery prehistory. It is easy to take water for granted, the deceptively simple molecule H2O has remarkable properties of great importance for rock and mineral weathering (Cookie 1). These include its solvent and hydration properties, wetting effects due to high saturation and anomalous decreaseofdensityatlow liquid temperatures and after freezing. An outline of the near-surface terrestrial hydrological cycle is given in Fig. 1.1.
Want to know more about the structure and properties of water? Turn to Cookie 1.
Chemical weathering involves aqueous reactions with a strong biochemical component since dissolved atmospheric gases are aided by soil-generated gases, dilute acids and organic ligands. Further, the reactions are complex since silicate minerals are involved, with their many constituent anions and cations; also the amount of water and dissolved ions varies in both time and space. Four main mechanisms contribute to chemical weathering: dissolution, oxidation, hydrolysis and acid hydrolysis. Reactions usually occur at mineral surfaces in the unsaturated (vadose) zone where, close to the local Earthās surface, rock pores contain atmospheric gases, water, living and dead vegetation and bacteriaāall play an important role in weathering. The result is a regolith and soil profile whose characteristics depend upon climate and rock type.
Physical weathering involves the application of differential stresses to rock and mineral discontinuities in the unsaturated zone. These cause fragmentation and are due to erosional unloading, gravity, wind shear, salt crystallization from groundwaters, freezeāthaw and differential thermal expansion.
The combined effects of biochemical and physical weathering produce a weathered regolith profile in bedrock that comprises:
- surface soil with significant living and dead organic content;
- chemically altered rock termed saprolite that nevertheless preserves its framework coherency without volume loss (isovolumetric weathering);
- chemically unaltered but often physically fragmented (exfoliated) bedrock.
Interfaces between these layers are in a state of slow downward motion as the landscape reduces. In fact, landscape dating by cosmogenic isotopes and other means reveals that a steady-state system often exists, with the material mass removed by erosion being replaced by an equal volume made available from below for further decomposition.
Weathering acts on:
- mineral aggregates at or close to Earthās surface with their many intracrystalline pores and fracture networks;
- imperfect crystals with surface and lattice defects.
Weathering involves:
- bond breaking, physically by cracking and chemically by solution (see Cookie 2);
- broken bond (danglers) adoption by ionic predators;
- electron removal from the easily stripped transition metals like Fe and Mn (see Cookie 3).
Weathering depends on:
- H2O throughput or hydraulic conductivity by laminar water flow in pore spaces between minerals, microporosity within minerals and cracks across minerals;
- H2O dissociation into the reactive H and OH ions (see Cookie 1);
- CO2 concentration via atmospheric and soil processes;
- temperature, which controls both reaction rates (Fig. 1.2) in silicate minerals via the results of the Arrhenius principle (see Cookie 3 and further below) and the rate of aqueous throughput via its control on waterās dynamic viscosity.